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901_16 | Uses and precautions
{| class="wikitable"
|+ Several 211At-containing molecules and their experimental uses
! Agent
! Applications
|-
| [211At]astatine-tellurium colloids
| Compartmental tumors
|-
| 6-[211At]astato-2-methyl-1,4-naphtaquinol diphosphate
| Adenocarcinomas
|-
| 211At-labeled methylene blue
| Melanomas
|-
| Meta-[211At]astatobenzyl guanidine
| Neuroendocrine tumors
|-
| 5-[211At]astato-2'-deoxyuridine
| Various
|-
| 211At-labeled biotin conjugates
| Various pretargeting
|-
| 211At-labeled octreotide
| Somatostatin receptor
|-
| 211At-labeled monoclonal antibodies and fragments
| Various
|-
| 211At-labeled bisphosphonates
| Bone metastases
|}
Newly formed astatine-211 is the subject of ongoing research in nuclear medicine. It must be used quickly as it decays with a half-life of 7.2 hours; this is long enough to permit multistep labeling strategies. Astatine-211 has potential for targeted alpha-particle therapy, since it decays either via emission of an alpha particle (to bismuth-207), or via electron capture (to an extremely short-lived nuclide, polonium-211, which undergoes further alpha decay), very quickly reaching its stable granddaughter lead-207. Polonium X-rays emitted as a result of the electron capture branch, in the range of 77–92 keV, enable the tracking of astatine in animals and patients. Although astatine-210 has a slightly longer half-life, it is wholly unsuitable because it usually undergoes beta plus decay to the extremely toxic polonium-210. | [
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901_17 | The principal medicinal difference between astatine-211 and iodine-131 (a radioactive iodine isotope also used in medicine) is that iodine-131 emits high-energy beta particles, and astatine does not. Beta particles have much greater penetrating power through tissues than do the much heavier alpha particles. An average alpha particle released by astatine-211 can travel up to 70 µm through surrounding tissues; an average-energy beta particle emitted by iodine-131 can travel nearly 30 times as far, to about 2 mm. The short half-life and limited penetrating power of alpha radiation through tissues offers advantages in situations where the "tumor burden is low and/or malignant cell populations are located in close proximity to essential normal tissues." Significant morbidity in cell culture models of human cancers has been achieved with from one to ten astatine-211 atoms bound per cell.
Several obstacles have been encountered in the development of astatine-based radiopharmaceuticals for cancer treatment. World War II delayed research for close to a decade. Results of early experiments indicated that a cancer-selective carrier would need to be developed and it was not until the 1970s that monoclonal antibodies became available for this purpose. Unlike iodine, astatine shows a tendency to dehalogenate from molecular carriers such as these, particularly at sp3 carbon sites (less so from sp2 sites). Given the toxicity of astatine accumulated and retained in the body, this emphasized the need to ensure it remained attached to its host molecule. While astatine carriers that are slowly metabolized can be assessed for their efficacy, more rapidly metabolized carriers remain a significant obstacle to the evaluation of astatine in nuclear medicine. Mitigating the effects of astatine-induced radiolysis of labeling chemistry and carrier molecules is another area requiring further development. A practical application for astatine as a cancer treatment would potentially be suitable for a "staggering" number of patients; production of astatine in the quantities that would be required remains an issue. | [
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901_18 | Animal studies show that astatine, similarly to iodine – although to a lesser extent, perhaps because of its slightly more metallic nature – is preferentially (and dangerously) concentrated in the thyroid gland. Unlike iodine, astatine also shows a tendency to be taken up by the lungs and spleen, possibly because of in-body oxidation of At– to At+. If administered in the form of a radiocolloid it tends to concentrate in the liver. Experiments in rats and monkeys suggest that astatine-211 causes much greater damage to the thyroid gland than does iodine-131, with repetitive injection of the nuclide resulting in necrosis and cell dysplasia within the gland. Early research suggested that injection of astatine into female rodents caused morphological changes in breast tissue; this conclusion remained controversial for many years. General agreement was later reached that this was likely caused by the effect of breast tissue irradiation combined with hormonal changes due to irradiation of the ovaries. Trace amounts of astatine can be handled safely in fume hoods if they are well-aerated; biological uptake of the element must be avoided.
See also
Radiation protection
Notes
References
Bibliography
External links
Astatine at The Periodic Table of Videos (University of Nottingham)
Astatine: Halogen or Metal?
Halogens
Metalloids
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902_0 | An atom is the smallest unit of ordinary matter that forms a chemical element. Every solid, liquid, gas, and plasma is composed of neutral or ionized atoms. Atoms are extremely small, typically around 100 picometers across. They are so small that accurately predicting their behavior using classical physics—as if they were tennis balls, for example—is not possible due to quantum effects.
Every atom is composed of a nucleus and one or more electrons bound to the nucleus. The nucleus is made of one or more protons and a number of neutrons. Only the most common variety of hydrogen has no neutrons. More than 99.94% of an atom's mass is in the nucleus. The protons have a positive electric charge, the electrons have a negative electric charge, and the neutrons have no electric charge. If the number of protons and electrons are equal, then the atom is electrically neutral. If an atom has more or fewer electrons than protons, then it has an overall negative or positive charge, respectively – such atoms are called ions.
The electrons of an atom are attracted to the protons in an atomic nucleus by the electromagnetic force. The protons and neutrons in the nucleus are attracted to each other by the nuclear force. This force is usually stronger than the electromagnetic force that repels the positively charged protons from one another. Under certain circumstances, the repelling electromagnetic force becomes stronger than the nuclear force. In this case, the nucleus splits and leaves behind different elements. This is a form of nuclear decay.
The number of protons in the nucleus is the atomic number and it defines to which chemical element the atom belongs. For example, any atom that contains 29 protons is copper. The number of neutrons defines the isotope of the element. Atoms can attach to one or more other atoms by chemical bonds to form chemical compounds such as molecules or crystals. The ability of atoms to associate and dissociate is responsible for most of the physical changes observed in nature. Chemistry is the discipline that studies these changes.
History of atomic theory
In philosophy | [
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902_1 | History of atomic theory
In philosophy
The basic idea that matter is made up of tiny, indivisible particles appears in many ancient cultures such as those of Greece and India. The word atom is derived from the ancient Greek word atomos (a combination of the negative term "a-" and "τομή," the term for "cut") that means "uncuttable". This ancient idea was based in philosophical reasoning rather than scientific reasoning; modern atomic theory is not based on these old concepts. Nonetheless, the term "atom" was used throughout the ages by thinkers who suspected that matter was ultimately granular in nature. It has since been discovered that "atoms" can be split, but the misnomer is still used.
Dalton's law of multiple proportions
In the early 1800s, the English chemist John Dalton compiled experimental data gathered by himself and other scientists and discovered a pattern now known as the "law of multiple proportions". He noticed that in chemical compounds which contain a particular chemical element, the content of that element in these compounds will differ by ratios of small whole numbers. This pattern suggested to Dalton that each chemical element combines with other elements by some basic and consistent unit of mass.
For example, there are two types of tin oxide: one is a black powder that is 88.1% tin and 11.9% oxygen, and the other is a white powder that is 78.7% tin and 21.3% oxygen. Adjusting these figures, in the black oxide there is about 13.5 g of oxygen for every 100 g of tin, and in the white oxide there is about 27 g of oxygen for every 100 g of tin. 13.5 and 27 form a ratio of 1:2. In these oxides, for every tin atom there are one or two oxygen atoms respectively (SnO and SnO2). | [
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902_2 | As a second example, Dalton considered two iron oxides: a black powder which is 78.1% iron and 21.9% oxygen, and a red powder which is 70.4% iron and 29.6% oxygen. Adjusting these figures, in the black oxide there is about 28 g of oxygen for every 100 g of iron, and in the red oxide there is about 42 g of oxygen for every 100 g of iron. 28 and 42 form a ratio of 2:3. In these respective oxides, for every two atoms of iron, there are two or three atoms of oxygen (Fe2O2 and Fe2O3).
As a final example: nitrous oxide is 63.3% nitrogen and 36.7% oxygen, nitric oxide is 44.05% nitrogen and 55.95% oxygen, and nitrogen dioxide is 29.5% nitrogen and 70.5% oxygen. Adjusting these figures, in nitrous oxide there is 80 g of oxygen for every 140 g of nitrogen, in nitric oxide there is about 160 g of oxygen for every 140 g of nitrogen, and in nitrogen dioxide there is 320 g of oxygen for every 140 g of nitrogen. 80, 160, and 320 form a ratio of 1:2:4. The respective formulas for these oxides are N2O, NO, and NO2.
Kinetic theory of gases
In the late 18th century, a number of scientists found that they could better explain the behavior of gases by describing them as collections of sub-microscopic particles and modelling their behavior using statistics and probability. Unlike Dalton's atomic theory, the kinetic theory of gases describes not how gases react chemically with each other to form compounds, but how they behave physically: diffusion, viscosity, conductivity, pressure, etc.
Brownian motion
In 1827, botanist Robert Brown used a microscope to look at dust grains floating in water and discovered that they moved about erratically, a phenomenon that became known as "Brownian motion". This was thought to be caused by water molecules knocking the grains about. In 1905, Albert Einstein proved the reality of these molecules and their motions by producing the first statistical physics analysis of Brownian motion. French physicist Jean Perrin used Einstein's work to experimentally determine the mass and dimensions of molecules, thereby providing physical evidence for the particle nature of matter.
Discovery of the electron | [
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902_3 | Discovery of the electron
In 1897, J. J. Thomson discovered that cathode rays are not electromagnetic waves but made of particles that are 1,800 times lighter than hydrogen (the lightest atom). Thomson concluded that these particles came from the atoms within the cathode — they were subatomic particles. He called these new particles corpuscles but they were later renamed electrons. Thomson also showed that electrons were identical to particles given off by photoelectric and radioactive materials. It was quickly recognized that electrons are the particles that carry electric currents in metal wires. Thomson concluded that these electrons emerged from the very atoms of the cathode in his instruments, which meant that atoms are not indivisible as the name atomos suggests.
Discovery of the nucleus
J. J. Thomson thought that the negatively-charged electrons were distributed throughout the atom in a sea of positive charge that was distributed across the whole volume of the atom. This model is sometimes known as the plum pudding model.
Ernest Rutherford and his colleagues Hans Geiger and Ernest Marsden came to have doubts about the Thomson model after they encountered difficulties when they tried to build an instrument to measure the charge-to-mass ratio of alpha particles (these are positively-charged particles emitted by certain radioactive substances such as radium). The alpha particles were being scattered by the air in the detection chamber, which made the measurements unreliable. Thomson had encountered a similar problem in his work on cathode rays, which he solved by creating a near-perfect vacuum in his instruments. Rutherford didn't think he'd run into this same problem because alpha particles are much heavier than electrons. According to Thomson's model of the atom, the positive charge in the atom is not concentrated enough to produce an electric field strong enough to deflect an alpha particle, and the electrons are so lightweight they should be pushed aside effortlessly by the much heavier alpha particles. Yet there was scattering, so Rutherford and his colleagues decided to investigate this scattering carefully. | [
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902_4 | Between 1908 and 1913, Rutheford and his colleagues performed a series of experiments in which they bombarded thin foils of metal with alpha particles. They spotted alpha particles being deflected by angles greater than 90°. To explain this, Rutherford proposed that the positive charge of the atom is not distributed throughout the atom's volume as Thomson believed, but is concentrated in a tiny nucleus at the center. Only such an intense concentration of charge could produce an electric field strong enough to deflect the alpha particles as observed.
Discovery of isotopes
While experimenting with the products of radioactive decay, in 1913 radiochemist Frederick Soddy discovered that there appeared to be more than one type of atom at each position on the periodic table. The term isotope was coined by Margaret Todd as a suitable name for different atoms that belong to the same element. J. J. Thomson created a technique for isotope separation through his work on ionized gases, which subsequently led to the discovery of stable isotopes.
Bohr model
In 1913, the physicist Niels Bohr proposed a model in which the electrons of an atom were assumed to orbit the nucleus but could only do so in a finite set of orbits, and could jump between these orbits only in discrete changes of energy corresponding to absorption or radiation of a photon. This quantization was used to explain why the electrons' orbits are stable (given that normally, charges in acceleration, including circular motion, lose kinetic energy which is emitted as electromagnetic radiation, see synchrotron radiation) and why elements absorb and emit electromagnetic radiation in discrete spectra.
Later in the same year Henry Moseley provided additional experimental evidence in favor of Niels Bohr's theory. These results refined Ernest Rutherford's and Antonius van den Broek's model, which proposed that the atom contains in its nucleus a number of positive nuclear charges that is equal to its (atomic) number in the periodic table. Until these experiments, atomic number was not known to be a physical and experimental quantity. That it is equal to the atomic nuclear charge remains the accepted atomic model today. | [
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902_5 | Chemical bonds between atoms were explained by Gilbert Newton Lewis in 1916, as the interactions between their constituent electrons. As the chemical properties of the elements were known to largely repeat themselves according to the periodic law, in 1919 the American chemist Irving Langmuir suggested that this could be explained if the electrons in an atom were connected or clustered in some manner. Groups of electrons were thought to occupy a set of electron shells about the nucleus.
The Bohr model of the atom was the first complete physical model of the atom. It described the overall structure of the atom, how atoms bond to each other, and predicted the spectral lines of hydrogen. Bohr's model was not perfect and was soon superseded by the more accurate Schrödinger model, but it was sufficient to evaporate any remaining doubts that matter is composed of atoms. For chemists, the idea of the atom had been a useful heuristic tool, but physicists had doubts as to whether matter really is made up of atoms as nobody had yet developed a complete physical model of the atom.
The Schrödinger model
The Stern–Gerlach experiment of 1922 provided further evidence of the quantum nature of atomic properties. When a beam of silver atoms was passed through a specially shaped magnetic field, the beam was split in a way correlated with the direction of an atom's angular momentum, or spin. As this spin direction is initially random, the beam would be expected to deflect in a random direction. Instead, the beam was split into two directional components, corresponding to the atomic spin being oriented up or down with respect to the magnetic field.
In 1925, Werner Heisenberg published the first consistent mathematical formulation of quantum mechanics (matrix mechanics). One year earlier, Louis de Broglie had proposed the de Broglie hypothesis: that all particles behave like waves to some extent, and in 1926 Erwin Schrödinger used this idea to develop the Schrödinger equation, a mathematical model of the atom (wave mechanics) that described the electrons as three-dimensional waveforms rather than point particles. | [
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902_6 | A consequence of using waveforms to describe particles is that it is mathematically impossible to obtain precise values for both the position and momentum of a particle at a given point in time; this became known as the uncertainty principle, formulated by Werner Heisenberg in 1927. In this concept, for a given accuracy in measuring a position one could only obtain a range of probable values for momentum, and vice versa.
This model was able to explain observations of atomic behavior that previous models could not, such as certain structural and spectral patterns of atoms larger than hydrogen. Thus, the planetary model of the atom was discarded in favor of one that described atomic orbital zones around the nucleus where a given electron is most likely to be observed.
Discovery of the neutron
The development of the mass spectrometer allowed the mass of atoms to be measured with increased accuracy. The device uses a magnet to bend the trajectory of a beam of ions, and the amount of deflection is determined by the ratio of an atom's mass to its charge. The chemist Francis William Aston used this instrument to show that isotopes had different masses. The atomic mass of these isotopes varied by integer amounts, called the whole number rule. The explanation for these different isotopes awaited the discovery of the neutron, an uncharged particle with a mass similar to the proton, by the physicist James Chadwick in 1932. Isotopes were then explained as elements with the same number of protons, but different numbers of neutrons within the nucleus.
Fission, high-energy physics and condensed matter
In 1938, the German chemist Otto Hahn, a student of Rutherford, directed neutrons onto uranium atoms expecting to get transuranium elements. Instead, his chemical experiments showed barium as a product. A year later, Lise Meitner and her nephew Otto Frisch verified that Hahn's result were the first experimental nuclear fission. In 1944, Hahn received the Nobel Prize in Chemistry. Despite Hahn's efforts, the contributions of Meitner and Frisch were not recognized.
In the 1950s, the development of improved particle accelerators and particle detectors allowed scientists to study the impacts of atoms moving at high energies. Neutrons and protons were found to be hadrons, or composites of smaller particles called quarks. The standard model of particle physics was developed that so far has successfully explained the properties of the nucleus in terms of these sub-atomic particles and the forces that govern their interactions.
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] |
902_7 | Structure
Subatomic particles
Though the word atom originally denoted a particle that cannot be cut into smaller particles, in modern scientific usage the atom is composed of various subatomic particles. The constituent particles of an atom are the electron, the proton and the neutron.
The electron is by far the least massive of these particles at , with a negative electrical charge and a size that is too small to be measured using available techniques. It was the lightest particle with a positive rest mass measured, until the discovery of neutrino mass. Under ordinary conditions, electrons are bound to the positively charged nucleus by the attraction created from opposite electric charges. If an atom has more or fewer electrons than its atomic number, then it becomes respectively negatively or positively charged as a whole; a charged atom is called an ion. Electrons have been known since the late 19th century, mostly thanks to J.J. Thomson; see history of subatomic physics for details.
Protons have a positive charge and a mass 1,836 times that of the electron, at . The number of protons in an atom is called its atomic number. Ernest Rutherford (1919) observed that nitrogen under alpha-particle bombardment ejects what appeared to be hydrogen nuclei. By 1920 he had accepted that the hydrogen nucleus is a distinct particle within the atom and named it proton.
Neutrons have no electrical charge and have a free mass of 1,839 times the mass of the electron, or . Neutrons are the heaviest of the three constituent particles, but their mass can be reduced by the nuclear binding energy. Neutrons and protons (collectively known as nucleons) have comparable dimensions—on the order of —although the 'surface' of these particles is not sharply defined. The neutron was discovered in 1932 by the English physicist James Chadwick.
In the Standard Model of physics, electrons are truly elementary particles with no internal structure, whereas protons and neutrons are composite particles composed of elementary particles called quarks. There are two types of quarks in atoms, each having a fractional electric charge. Protons are composed of two up quarks (each with charge +) and one down quark (with a charge of −). Neutrons consist of one up quark and two down quarks. This distinction accounts for the difference in mass and charge between the two particles. | [
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902_8 | The quarks are held together by the strong interaction (or strong force), which is mediated by gluons. The protons and neutrons, in turn, are held to each other in the nucleus by the nuclear force, which is a residuum of the strong force that has somewhat different range-properties (see the article on the nuclear force for more). The gluon is a member of the family of gauge bosons, which are elementary particles that mediate physical forces.
Nucleus
All the bound protons and neutrons in an atom make up a tiny atomic nucleus, and are collectively called nucleons. The radius of a nucleus is approximately equal to femtometres, where is the total number of nucleons. This is much smaller than the radius of the atom, which is on the order of 105 fm. The nucleons are bound together by a short-ranged attractive potential called the residual strong force. At distances smaller than 2.5 fm this force is much more powerful than the electrostatic force that causes positively charged protons to repel each other.
Atoms of the same element have the same number of protons, called the atomic number. Within a single element, the number of neutrons may vary, determining the isotope of that element. The total number of protons and neutrons determine the nuclide. The number of neutrons relative to the protons determines the stability of the nucleus, with certain isotopes undergoing radioactive decay.
The proton, the electron, and the neutron are classified as fermions. Fermions obey the Pauli exclusion principle which prohibits identical fermions, such as multiple protons, from occupying the same quantum state at the same time. Thus, every proton in the nucleus must occupy a quantum state different from all other protons, and the same applies to all neutrons of the nucleus and to all electrons of the electron cloud.
A nucleus that has a different number of protons than neutrons can potentially drop to a lower energy state through a radioactive decay that causes the number of protons and neutrons to more closely match. As a result, atoms with matching numbers of protons and neutrons are more stable against decay, but with increasing atomic number, the mutual repulsion of the protons requires an increasing proportion of neutrons to maintain the stability of the nucleus. | [
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902_9 | The number of protons and neutrons in the atomic nucleus can be modified, although this can require very high energies because of the strong force. Nuclear fusion occurs when multiple atomic particles join to form a heavier nucleus, such as through the energetic collision of two nuclei. For example, at the core of the Sun protons require energies of 3 to 10 keV to overcome their mutual repulsion—the coulomb barrier—and fuse together into a single nucleus. Nuclear fission is the opposite process, causing a nucleus to split into two smaller nuclei—usually through radioactive decay. The nucleus can also be modified through bombardment by high energy subatomic particles or photons. If this modifies the number of protons in a nucleus, the atom changes to a different chemical element.
If the mass of the nucleus following a fusion reaction is less than the sum of the masses of the separate particles, then the difference between these two values can be emitted as a type of usable energy (such as a gamma ray, or the kinetic energy of a beta particle), as described by Albert Einstein's mass-energy equivalence formula, , where is the mass loss and is the speed of light. This deficit is part of the binding energy of the new nucleus, and it is the non-recoverable loss of the energy that causes the fused particles to remain together in a state that requires this energy to separate.
The fusion of two nuclei that create larger nuclei with lower atomic numbers than iron and nickel—a total nucleon number of about 60—is usually an exothermic process that releases more energy than is required to bring them together. It is this energy-releasing process that makes nuclear fusion in stars a self-sustaining reaction. For heavier nuclei, the binding energy per nucleon in the nucleus begins to decrease. That means fusion processes producing nuclei that have atomic numbers higher than about 26, and atomic masses higher than about 60, is an endothermic process. These more massive nuclei can not undergo an energy-producing fusion reaction that can sustain the hydrostatic equilibrium of a star.
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] |
902_10 | Electron cloud
The electrons in an atom are attracted to the protons in the nucleus by the electromagnetic force. This force binds the electrons inside an electrostatic potential well surrounding the smaller nucleus, which means that an external source of energy is needed for the electron to escape. The closer an electron is to the nucleus, the greater the attractive force. Hence electrons bound near the center of the potential well require more energy to escape than those at greater separations.
Electrons, like other particles, have properties of both a particle and a wave. The electron cloud is a region inside the potential well where each electron forms a type of three-dimensional standing wave—a wave form that does not move relative to the nucleus. This behavior is defined by an atomic orbital, a mathematical function that characterises the probability that an electron appears to be at a particular location when its position is measured. Only a discrete (or quantized) set of these orbitals exist around the nucleus, as other possible wave patterns rapidly decay into a more stable form. Orbitals can have one or more ring or node structures, and differ from each other in size, shape and orientation.
Each atomic orbital corresponds to a particular energy level of the electron. The electron can change its state to a higher energy level by absorbing a photon with sufficient energy to boost it into the new quantum state. Likewise, through spontaneous emission, an electron in a higher energy state can drop to a lower energy state while radiating the excess energy as a photon. These characteristic energy values, defined by the differences in the energies of the quantum states, are responsible for atomic spectral lines.
The amount of energy needed to remove or add an electron—the electron binding energy—is far less than the binding energy of nucleons. For example, it requires only 13.6 eV to strip a ground-state electron from a hydrogen atom, compared to 2.23 million eV for splitting a deuterium nucleus. Atoms are electrically neutral if they have an equal number of protons and electrons. Atoms that have either a deficit or a surplus of electrons are called ions. Electrons that are farthest from the nucleus may be transferred to other nearby atoms or shared between atoms. By this mechanism, atoms are able to bond into molecules and other types of chemical compounds like ionic and covalent network crystals.
Properties
Nuclear properties | [
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] |
902_11 | Properties
Nuclear properties
By definition, any two atoms with an identical number of protons in their nuclei belong to the same chemical element. Atoms with equal numbers of protons but a different number of neutrons are different isotopes of the same element. For example, all hydrogen atoms admit exactly one proton, but isotopes exist with no neutrons (hydrogen-1, by far the most common form, also called protium), one neutron (deuterium), two neutrons (tritium) and more than two neutrons. The known elements form a set of atomic numbers, from the single-proton element hydrogen up to the 118-proton element oganesson. All known isotopes of elements with atomic numbers greater than 82 are radioactive, although the radioactivity of element 83 (bismuth) is so slight as to be practically negligible.
About 339 nuclides occur naturally on Earth, of which 252 (about 74%) have not been observed to decay, and are referred to as "stable isotopes". Only 90 nuclides are stable theoretically, while another 162 (bringing the total to 252) have not been observed to decay, even though in theory it is energetically possible. These are also formally classified as "stable". An additional 34 radioactive nuclides have half-lives longer than 100 million years, and are long-lived enough to have been present since the birth of the Solar System. This collection of 286 nuclides are known as primordial nuclides. Finally, an additional 53 short-lived nuclides are known to occur naturally, as daughter products of primordial nuclide decay (such as radium from uranium), or as products of natural energetic processes on Earth, such as cosmic ray bombardment (for example, carbon-14).
For 80 of the chemical elements, at least one stable isotope exists. As a rule, there is only a handful of stable isotopes for each of these elements, the average being 3.2 stable isotopes per element. Twenty-six elements have only a single stable isotope, while the largest number of stable isotopes observed for any element is ten, for the element tin. Elements 43, 61, and all elements numbered 83 or higher have no stable isotopes. | [
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902_12 | Stability of isotopes is affected by the ratio of protons to neutrons, and also by the presence of certain "magic numbers" of neutrons or protons that represent closed and filled quantum shells. These quantum shells correspond to a set of energy levels within the shell model of the nucleus; filled shells, such as the filled shell of 50 protons for tin, confers unusual stability on the nuclide. Of the 252 known stable nuclides, only four have both an odd number of protons and odd number of neutrons: hydrogen-2 (deuterium), lithium-6, boron-10 and nitrogen-14. Also, only four naturally occurring, radioactive odd-odd nuclides have a half-life over a billion years: potassium-40, vanadium-50, lanthanum-138 and tantalum-180m. Most odd-odd nuclei are highly unstable with respect to beta decay, because the decay products are even-even, and are therefore more strongly bound, due to nuclear pairing effects.
Mass
The large majority of an atom's mass comes from the protons and neutrons that make it up. The total number of these particles (called "nucleons") in a given atom is called the mass number. It is a positive integer and dimensionless (instead of having dimension of mass), because it expresses a count. An example of use of a mass number is "carbon-12," which has 12 nucleons (six protons and six neutrons).
The actual mass of an atom at rest is often expressed in daltons (Da), also called the unified atomic mass unit (u). This unit is defined as a twelfth of the mass of a free neutral atom of carbon-12, which is approximately . Hydrogen-1 (the lightest isotope of hydrogen which is also the nuclide with the lowest mass) has an atomic weight of 1.007825 Da. The value of this number is called the atomic mass. A given atom has an atomic mass approximately equal (within 1%) to its mass number times the atomic mass unit (for example the mass of a nitrogen-14 is roughly 14 Da), but this number will not be exactly an integer except (by definition) in the case of carbon-12. The heaviest stable atom is lead-208, with a mass of . | [
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902_13 | As even the most massive atoms are far too light to work with directly, chemists instead use the unit of moles. One mole of atoms of any element always has the same number of atoms (about ). This number was chosen so that if an element has an atomic mass of 1 u, a mole of atoms of that element has a mass close to one gram. Because of the definition of the unified atomic mass unit, each carbon-12 atom has an atomic mass of exactly 12 Da, and so a mole of carbon-12 atoms weighs exactly 0.012 kg.
Shape and size
Atoms lack a well-defined outer boundary, so their dimensions are usually described in terms of an atomic radius. This is a measure of the distance out to which the electron cloud extends from the nucleus. This assumes the atom to exhibit a spherical shape, which is only obeyed for atoms in vacuum or free space. Atomic radii may be derived from the distances between two nuclei when the two atoms are joined in a chemical bond. The radius varies with the location of an atom on the atomic chart, the type of chemical bond, the number of neighboring atoms (coordination number) and a quantum mechanical property known as spin. On the periodic table of the elements, atom size tends to increase when moving down columns, but decrease when moving across rows (left to right). Consequently, the smallest atom is helium with a radius of 32 pm, while one of the largest is caesium at 225 pm.
When subjected to external forces, like electrical fields, the shape of an atom may deviate from spherical symmetry. The deformation depends on the field magnitude and the orbital type of outer shell electrons, as shown by group-theoretical considerations. Aspherical deviations might be elicited for instance in crystals, where large crystal-electrical fields may occur at low-symmetry lattice sites. Significant ellipsoidal deformations have been shown to occur for sulfur ions and chalcogen ions in pyrite-type compounds. | [
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902_14 | Atomic dimensions are thousands of times smaller than the wavelengths of light (400–700 nm) so they cannot be viewed using an optical microscope, although individual atoms can be observed using a scanning tunneling microscope. To visualize the minuteness of the atom, consider that a typical human hair is about 1 million carbon atoms in width. A single drop of water contains about 2 sextillion () atoms of oxygen, and twice the number of hydrogen atoms. A single carat diamond with a mass of contains about 10 sextillion (1022) atoms of carbon. If an apple were magnified to the size of the Earth, then the atoms in the apple would be approximately the size of the original apple.
Radioactive decay
Every element has one or more isotopes that have unstable nuclei that are subject to radioactive decay, causing the nucleus to emit particles or electromagnetic radiation. Radioactivity can occur when the radius of a nucleus is large compared with the radius of the strong force, which only acts over distances on the order of 1 fm.
The most common forms of radioactive decay are:
Alpha decay: this process is caused when the nucleus emits an alpha particle, which is a helium nucleus consisting of two protons and two neutrons. The result of the emission is a new element with a lower atomic number.
Beta decay (and electron capture): these processes are regulated by the weak force, and result from a transformation of a neutron into a proton, or a proton into a neutron. The neutron to proton transition is accompanied by the emission of an electron and an antineutrino, while proton to neutron transition (except in electron capture) causes the emission of a positron and a neutrino. The electron or positron emissions are called beta particles. Beta decay either increases or decreases the atomic number of the nucleus by one. Electron capture is more common than positron emission, because it requires less energy. In this type of decay, an electron is absorbed by the nucleus, rather than a positron emitted from the nucleus. A neutrino is still emitted in this process, and a proton changes to a neutron.
Gamma decay: this process results from a change in the energy level of the nucleus to a lower state, resulting in the emission of electromagnetic radiation. The excited state of a nucleus which results in gamma emission usually occurs following the emission of an alpha or a beta particle. Thus, gamma decay usually follows alpha or beta decay. | [
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902_15 | Other more rare types of radioactive decay include ejection of neutrons or protons or clusters of nucleons from a nucleus, or more than one beta particle. An analog of gamma emission which allows excited nuclei to lose energy in a different way, is internal conversion—a process that produces high-speed electrons that are not beta rays, followed by production of high-energy photons that are not gamma rays. A few large nuclei explode into two or more charged fragments of varying masses plus several neutrons, in a decay called spontaneous nuclear fission.
Each radioactive isotope has a characteristic decay time period—the half-life—that is determined by the amount of time needed for half of a sample to decay. This is an exponential decay process that steadily decreases the proportion of the remaining isotope by 50% every half-life. Hence after two half-lives have passed only 25% of the isotope is present, and so forth.
Magnetic moment
Elementary particles possess an intrinsic quantum mechanical property known as spin. This is analogous to the angular momentum of an object that is spinning around its center of mass, although strictly speaking these particles are believed to be point-like and cannot be said to be rotating. Spin is measured in units of the reduced Planck constant (ħ), with electrons, protons and neutrons all having spin ½ ħ, or "spin-½". In an atom, electrons in motion around the nucleus possess orbital angular momentum in addition to their spin, while the nucleus itself possesses angular momentum due to its nuclear spin.
The magnetic field produced by an atom—its magnetic moment—is determined by these various forms of angular momentum, just as a rotating charged object classically produces a magnetic field, but the most dominant contribution comes from electron spin. Due to the nature of electrons to obey the Pauli exclusion principle, in which no two electrons may be found in the same quantum state, bound electrons pair up with each other, with one member of each pair in a spin up state and the other in the opposite, spin down state. Thus these spins cancel each other out, reducing the total magnetic dipole moment to zero in some atoms with even number of electrons. | [
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902_16 | In ferromagnetic elements such as iron, cobalt and nickel, an odd number of electrons leads to an unpaired electron and a net overall magnetic moment. The orbitals of neighboring atoms overlap and a lower energy state is achieved when the spins of unpaired electrons are aligned with each other, a spontaneous process known as an exchange interaction. When the magnetic moments of ferromagnetic atoms are lined up, the material can produce a measurable macroscopic field. Paramagnetic materials have atoms with magnetic moments that line up in random directions when no magnetic field is present, but the magnetic moments of the individual atoms line up in the presence of a field.
The nucleus of an atom will have no spin when it has even numbers of both neutrons and protons, but for other cases of odd numbers, the nucleus may have a spin. Normally nuclei with spin are aligned in random directions because of thermal equilibrium, but for certain elements (such as xenon-129) it is possible to polarize a significant proportion of the nuclear spin states so that they are aligned in the same direction—a condition called hyperpolarization. This has important applications in magnetic resonance imaging.
Energy levels
The potential energy of an electron in an atom is negative relative to when the distance from the nucleus goes to infinity; its dependence on the electron's position reaches the minimum inside the nucleus, roughly in inverse proportion to the distance. In the quantum-mechanical model, a bound electron can occupy only a set of states centered on the nucleus, and each state corresponds to a specific energy level; see time-independent Schrödinger equation for a theoretical explanation. An energy level can be measured by the amount of energy needed to unbind the electron from the atom, and is usually given in units of electronvolts (eV). The lowest energy state of a bound electron is called the ground state, i.e. stationary state, while an electron transition to a higher level results in an excited state. The electron's energy increases along with n because the (average) distance to the nucleus increases. Dependence of the energy on is caused not by the electrostatic potential of the nucleus, but by interaction between electrons. | [
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902_17 | For an electron to transition between two different states, e.g. ground state to first excited state, it must absorb or emit a photon at an energy matching the difference in the potential energy of those levels, according to the Niels Bohr model, what can be precisely calculated by the Schrödinger equation.
Electrons jump between orbitals in a particle-like fashion. For example, if a single photon strikes the electrons, only a single electron changes states in response to the photon; see Electron properties.
The energy of an emitted photon is proportional to its frequency, so these specific energy levels appear as distinct bands in the electromagnetic spectrum. Each element has a characteristic spectrum that can depend on the nuclear charge, subshells filled by electrons, the electromagnetic interactions between the electrons and other factors.
When a continuous spectrum of energy is passed through a gas or plasma, some of the photons are absorbed by atoms, causing electrons to change their energy level. Those excited electrons that remain bound to their atom spontaneously emit this energy as a photon, traveling in a random direction, and so drop back to lower energy levels. Thus the atoms behave like a filter that forms a series of dark absorption bands in the energy output. (An observer viewing the atoms from a view that does not include the continuous spectrum in the background, instead sees a series of emission lines from the photons emitted by the atoms.) Spectroscopic measurements of the strength and width of atomic spectral lines allow the composition and physical properties of a substance to be determined.
Close examination of the spectral lines reveals that some display a fine structure splitting. This occurs because of spin-orbit coupling, which is an interaction between the spin and motion of the outermost electron. When an atom is in an external magnetic field, spectral lines become split into three or more components; a phenomenon called the Zeeman effect. This is caused by the interaction of the magnetic field with the magnetic moment of the atom and its electrons. Some atoms can have multiple electron configurations with the same energy level, which thus appear as a single spectral line. The interaction of the magnetic field with the atom shifts these electron configurations to slightly different energy levels, resulting in multiple spectral lines. The presence of an external electric field can cause a comparable splitting and shifting of spectral lines by modifying the electron energy levels, a phenomenon called the Stark effect. | [
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902_18 | If a bound electron is in an excited state, an interacting photon with the proper energy can cause stimulated emission of a photon with a matching energy level. For this to occur, the electron must drop to a lower energy state that has an energy difference matching the energy of the interacting photon. The emitted photon and the interacting photon then move off in parallel and with matching phases. That is, the wave patterns of the two photons are synchronized. This physical property is used to make lasers, which can emit a coherent beam of light energy in a narrow frequency band.
Valence and bonding behavior
Valency is the combining power of an element. It is determined by the number of bonds it can form to other atoms or groups. The outermost electron shell of an atom in its uncombined state is known as the valence shell, and the electrons in
that shell are called valence electrons. The number of valence electrons determines the bonding
behavior with other atoms. Atoms tend to chemically react with each other in a manner that fills (or empties) their outer valence shells. For example, a transfer of a single electron between atoms is a useful approximation for bonds that form between atoms with one-electron more than a filled shell, and others that are one-electron short of a full shell, such as occurs in the compound sodium chloride and other chemical ionic salts. Many elements display multiple valences, or tendencies to share differing numbers of electrons in different compounds. Thus, chemical bonding between these elements takes many forms of electron-sharing that are more than simple electron transfers. Examples include the element carbon and the organic compounds.
The chemical elements are often displayed in a periodic table that is laid out to display recurring chemical properties, and elements with the same number of valence electrons form a group that is aligned in the same column of the table. (The horizontal rows correspond to the filling of a quantum shell of electrons.) The elements at the far right of the table have their outer shell completely filled with electrons, which results in chemically inert elements known as the noble gases.
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902_19 | States
Quantities of atoms are found in different states of matter that depend on the physical conditions, such as temperature and pressure. By varying the conditions, materials can transition between solids, liquids, gases and plasmas. Within a state, a material can also exist in different allotropes. An example of this is solid carbon, which can exist as graphite or diamond. Gaseous allotropes exist as well, such as dioxygen and ozone.
At temperatures close to absolute zero, atoms can form a Bose–Einstein condensate, at which point quantum mechanical effects, which are normally only observed at the atomic scale, become apparent on a macroscopic scale. This super-cooled collection of atoms
then behaves as a single super atom, which may allow fundamental checks of quantum mechanical behavior.
Identification
While atoms are too small to be seen, devices such as the scanning tunneling microscope (STM) enable their visualization at the surfaces of solids. The microscope uses the quantum tunneling phenomenon, which allows particles to pass through a barrier that would be insurmountable in the classical perspective. Electrons tunnel through the vacuum between two biased electrodes, providing a tunneling current that is exponentially dependent on their separation. One electrode is a sharp tip ideally ending with a single atom. At each point of the scan of the surface the tip's height is adjusted so as to keep the tunneling current at a set value. How much the tip moves to and away from the surface is interpreted as the height profile. For low bias, the microscope images the averaged electron orbitals across closely packed energy levels—the local density of the electronic states near the Fermi level. Because of the distances involved, both electrodes need to be extremely stable; only then periodicities can be observed that correspond to individual atoms. The method alone is not chemically specific, and cannot identify the atomic species present at the surface. | [
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902_20 | Atoms can be easily identified by their mass. If an atom is ionized by removing one of its electrons, its trajectory when it passes through a magnetic field will bend. The radius by which the trajectory of a moving ion is turned by the magnetic field is determined by the mass of the atom. The mass spectrometer uses this principle to measure the mass-to-charge ratio of ions. If a sample contains multiple isotopes, the mass spectrometer can determine the proportion of each isotope in the sample by measuring the intensity of the different beams of ions. Techniques to vaporize atoms include inductively coupled plasma atomic emission spectroscopy and inductively coupled plasma mass spectrometry, both of which use a plasma to vaporize samples for analysis.
The atom-probe tomograph has sub-nanometer resolution in 3-D and can chemically identify individual atoms using time-of-flight mass spectrometry.
Electron emission techniques such as X-ray photoelectron spectroscopy (XPS) and Auger electron spectroscopy (AES), which measure the binding energies of the core electrons, are used to identify the atomic species present in a sample in a non-destructive way. With proper focusing both can be made area-specific. Another such method is electron energy loss spectroscopy (EELS), which measures the energy loss of an electron beam within a transmission electron microscope when it interacts with a portion of a sample.
Spectra of excited states can be used to analyze the atomic composition of distant stars. Specific light wavelengths contained in the observed light from stars can be separated out and related to the quantized transitions in free gas atoms. These colors can be replicated using a gas-discharge lamp containing the same element. Helium was discovered in this way in the spectrum of the Sun 23 years before it was found on Earth. | [
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902_21 | Origin and current state
Baryonic matter forms about 4% of the total energy density of the observable Universe, with an average density of about 0.25 particles/m3 (mostly protons and electrons). Within a galaxy such as the Milky Way, particles have a much higher concentration, with the density of matter in the interstellar medium (ISM) ranging from 105 to 109 atoms/m3. The Sun is believed to be inside the Local Bubble, so the density in the solar neighborhood is only about 103 atoms/m3. Stars form from dense clouds in the ISM, and the evolutionary processes of stars result in the steady enrichment of the ISM with elements more massive than hydrogen and helium.
Up to 95% of the Milky Way's baryonic matter are concentrated inside stars, where conditions are unfavorable for atomic matter. The total baryonic mass is about 10% of the mass of the galaxy; the remainder of the mass is an unknown dark matter. High temperature inside stars makes most "atoms" fully ionized, that is, separates all electrons from the nuclei. In stellar remnants—with exception of their surface layers—an immense pressure make electron shells impossible.
Formation
Electrons are thought to exist in the Universe since early stages of the Big Bang. Atomic nuclei forms in nucleosynthesis reactions. In about three minutes Big Bang nucleosynthesis produced most of the helium, lithium, and deuterium in the Universe, and perhaps some of the beryllium and boron.
Ubiquitousness and stability of atoms relies on their binding energy, which means that an atom has a lower energy than an unbound system of the nucleus and electrons. Where the temperature is much higher than ionization potential, the matter exists in the form of plasma—a gas of positively charged ions (possibly, bare nuclei) and electrons. When the temperature drops below the ionization potential, atoms become statistically favorable. Atoms (complete with bound electrons) became to dominate over charged particles 380,000 years after the Big Bang—an epoch called recombination, when the expanding Universe cooled enough to allow electrons to become attached to nuclei. | [
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902_22 | Since the Big Bang, which produced no carbon or heavier elements, atomic nuclei have been combined in stars through the process of nuclear fusion to produce more of the element helium, and (via the triple alpha process) the sequence of elements from carbon up to iron; see stellar nucleosynthesis for details.
Isotopes such as lithium-6, as well as some beryllium and boron are generated in space through cosmic ray spallation. This occurs when a high-energy proton strikes an atomic nucleus, causing large numbers of nucleons to be ejected.
Elements heavier than iron were produced in supernovae and colliding neutron stars through the r-process, and in AGB stars through the s-process, both of which involve the capture of neutrons by atomic nuclei. Elements such as lead formed largely through the radioactive decay of heavier elements.
Earth
Most of the atoms that make up the Earth and its inhabitants were present in their current form in the nebula that collapsed out of a molecular cloud to form the Solar System. The rest are the result of radioactive decay, and their relative proportion can be used to determine the age of the Earth through radiometric dating. Most of the helium in the crust of the Earth (about 99% of the helium from gas wells, as shown by its lower abundance of helium-3) is a product of alpha decay.
There are a few trace atoms on Earth that were not present at the beginning (i.e., not "primordial"), nor are results of radioactive decay. Carbon-14 is continuously generated by cosmic rays in the atmosphere. Some atoms on Earth have been artificially generated either deliberately or as by-products of nuclear reactors or explosions. Of the transuranic elements—those with atomic numbers greater than 92—only plutonium and neptunium occur naturally on Earth. Transuranic elements have radioactive lifetimes shorter than the current age of the Earth and thus identifiable quantities of these elements have long since decayed, with the exception of traces of plutonium-244 possibly deposited by cosmic dust. Natural deposits of plutonium and neptunium are produced by neutron capture in uranium ore. | [
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902_23 | The Earth contains approximately atoms. Although small numbers of independent atoms of noble gases exist, such as argon, neon, and helium, 99% of the atmosphere is bound in the form of molecules, including carbon dioxide and diatomic oxygen and nitrogen. At the surface of the Earth, an overwhelming majority of atoms combine to form various compounds, including water, salt, silicates and oxides. Atoms can also combine to create materials that do not consist of discrete molecules, including crystals and liquid or solid metals. This atomic matter forms networked arrangements that lack the particular type of small-scale interrupted order associated with molecular matter.
Rare and theoretical forms
Superheavy elements
All nuclides with atomic numbers higher than 82 (lead) are known to be radioactive. No nuclide with an atomic number exceeding 92 (uranium) exists on Earth as a primordial nuclide, and heavier elements generally have shorter half-lives. Nevertheless, an "island of stability" encompassing relatively long-lived isotopes of superheavy elements with atomic numbers 110 to 114 might exist. Predictions for the half-life of the most stable nuclide on the island range from a few minutes to millions of years. In any case, superheavy elements (with Z > 104) would not exist due to increasing Coulomb repulsion (which results in spontaneous fission with increasingly short half-lives) in the absence of any stabilizing effects.
Exotic matter
Each particle of matter has a corresponding antimatter particle with the opposite electrical charge. Thus, the positron is a positively charged antielectron and the antiproton is a negatively charged equivalent of a proton. When a matter and corresponding antimatter particle meet, they annihilate each other. Because of this, along with an imbalance between the number of matter and antimatter particles, the latter are rare in the universe. The first causes of this imbalance are not yet fully understood, although theories of baryogenesis may offer an explanation. As a result, no antimatter atoms have been discovered in nature. In 1996, the antimatter counterpart of the hydrogen atom (antihydrogen) was synthesized at the CERN laboratory in Geneva. | [
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902_24 | Other exotic atoms have been created by replacing one of the protons, neutrons or electrons with other particles that have the same charge. For example, an electron can be replaced by a more massive muon, forming a muonic atom. These types of atoms can be used to test fundamental predictions of physics.
See also
Notes
References
Bibliography
Further reading
External links
Chemistry
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903_0 | Arable land (from the , "able to be ploughed") is any land capable of being ploughed and used to grow crops. Alternatively, for the purposes of agricultural statistics, the term often has a more precise definition:
A more concise definition appearing in the Eurostat glossary similarly refers to actual rather than potential uses: "land worked (ploughed or tilled) regularly, generally under a system of crop rotation".
Non-arable land can sometimes be converted to arable land through methods such as loosening and tilling (breaking up) of the soil, though in more extreme cases the degree of modification required to make certain types of land arable can become prohibitively expensive.
In Britain, arable land has traditionally been contrasted with pasturable land such as heaths, which could be used for sheep-rearing but not as farmland.
Arable land area
According to the Food and Agriculture Organization of the United Nations, in 2013, the world's arable land amounted to 1.407 billion hectares, out of a total of 4.924 billion hectares of land used for agriculture.
Arable land (hectares per person)
Non-arable land
Agricultural land that is not arable according to the FAO definition above includes:
Meadows and pasturesland used as pasture and grazed range, and those natural grasslands and sedge meadows that are used for hay production in some regions.
Permanent cropland that produces crops from woody vegetation, e.g. orchard land, vineyards, coffee plantations, rubber plantations, and land producing nut trees; | [
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903_1 | Other non-arable land includes land that is not suitable for any agricultural use. Land that is not arable, in the sense of lacking capability or suitability for cultivation for crop production, has one or more limitationsa lack of sufficient freshwater for irrigation, stoniness, steepness, adverse climate, excessive wetness with the impracticality of drainage, excessive salts, or a combination of these, among others. Although such limitations may preclude cultivation, and some will in some cases preclude any agricultural use, large areas unsuitable for cultivation may still be agriculturally productive. For example, United States NRCS statistics indicate that about 59 percent of US non-federal pasture and unforested rangeland is unsuitable for cultivation, yet such land has value for grazing of livestock. In British Columbia, Canada, 41 percent of the provincial Agricultural Land Reserve area is unsuitable for the production of cultivated crops, but is suitable for uncultivated production of forage usable by grazing livestock. Similar examples can be found in many rangeland areas elsewhere.
Land incapable of being cultivated for the production of crops can sometimes be converted to arable land. New arable land makes more food and can reduce starvation. This outcome also makes a country more self-sufficient and politically independent, because food importation is reduced. Making non-arable land arable often involves digging new irrigation canals and new wells, aqueducts, desalination plants, planting trees for shade in the desert, hydroponics, fertilizer, nitrogen fertilizer, pesticides, reverse osmosis water processors, PET film insulation or other insulation against heat and cold, digging ditches and hills for protection against the wind, and installing greenhouses with internal light and heat for protection against the cold outside and to provide light in cloudy areas. Such modifications are often prohibitively expensive. An alternative is the seawater greenhouse, which desalinates water through evaporation and condensation using solar energy as the only energy input. This technology is optimized to grow crops on desert land close to the sea. | [
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903_2 | The use of artifices does not make the land arable. Rock still remains rock, and shallowless than turnable soil is still not considered toilable. The use of artifice is an open-air none recycled water hydroponics relationship. The below described circumstances are not in perspective, have limited duration, and have a tendency to accumulate trace materials in soil that either there or elsewhere cause deoxygenation. The use of vast amounts of fertilizer may have unintended consequences for the environment by devastating rivers, waterways, and river endings through the accumulation of non-degradable toxins and nitrogen-bearing molecules that remove oxygen and cause non-aerobic processes to form.
Examples of infertile non-arable land being turned into fertile arable land include:
Aran Islands: These islands off the west coast of Ireland (not to be confused with the Isle of Arran in Scotland's Firth of Clyde) were unsuitable for arable farming because they were too rocky. The people covered the islands with a shallow layer of seaweed and sand from the ocean. Today, crops are grown there, even though the islands are still considered non-arable.
Israel: The construction of desalination plants along Israel's coast allowed agriculture in some areas that were formerly desert. The desalination plants, which remove the salt from ocean water, have produced a new source of water for farming, drinking, and washing.
Slash and burn agriculture uses nutrients in wood ash, but these expire within a few years.
Terra preta, fertile tropical soils produced by adding charcoal.
Examples of fertile arable land being turned into infertile land include:
Droughts such as the "Dust Bowl" of the Great Depression in the US turned farmland into desert.
Each year, arable land is lost due to desertification and human-induced erosion. Improper irrigation of farmland can wick the sodium, calcium, and magnesium from the soil and water to the surface. This process steadily concentrates salt in the root zone, decreasing productivity for crops that are not salt-tolerant.
Rainforest deforestation: The fertile tropical forests are converted into infertile desert land. For example, Madagascar's central highland plateau has become virtually totally barren (about ten percent of the country) as a result of slash-and-burn deforestation, an element of shifting cultivation practiced by many natives. | [
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] |
903_3 | See also
Development easement
Land use statistics by country
List of environment topics
Soil fertility
References
External links
Article from Technorati on Shrinking Arable Farmland in the world
Surface area of the Earth
Agricultural land | [
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904_0 | Aluminium (or aluminum in American English and Canadian English) is a chemical element with the symbol Al and atomic number 13. Aluminium has a density lower than those of other common metals, at approximately one third that of steel. It has a great affinity towards oxygen, and forms a protective layer of oxide on the surface when exposed to air. Aluminium visually resembles silver, both in its color and in its great ability to reflect light. It is soft, non-magnetic and ductile. It has one stable isotope, 27Al; this isotope is very common, making aluminium the twelfth most common element in the Universe. The radioactivity of 26Al is used in radiodating.
Chemically, aluminium is a post-transition metal in the boron group; as is common for the group, aluminium forms compounds primarily in the +3 oxidation state. The aluminium cation Al3+ is small and highly charged; as such, it is polarizing, and bonds aluminium forms tend towards covalency. The strong affinity towards oxygen leads to aluminium's common association with oxygen in nature in the form of oxides; for this reason, aluminium is found on Earth primarily in rocks in the crust, where it is the third most abundant element after oxygen and silicon, rather than in the mantle, and virtually never as the free metal.
The discovery of aluminium was announced in 1825 by Danish physicist Hans Christian Ørsted. The first industrial production of aluminium was initiated by French chemist Henri Étienne Sainte-Claire Deville in 1856. Aluminium became much more available to the public with the Hall–Héroult process developed independently by French engineer Paul Héroult and American engineer Charles Martin Hall in 1886, and the mass production of aluminium led to its extensive use in industry and everyday life. In World Wars I and II, aluminium was a crucial strategic resource for aviation. In 1954, aluminium became the most produced non-ferrous metal, surpassing copper. In the 21st century, most aluminium was consumed in transportation, engineering, construction, and packaging in the United States, Western Europe, and Japan.
Despite its prevalence in the environment, no living organism is known to use aluminium salts metabolically, but aluminium is well tolerated by plants and animals. Because of the abundance of these salts, the potential for a biological role for them is of continuing interest, and studies continue.
Physical characteristics
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904_1 | Physical characteristics
Isotopes
Of aluminium isotopes, only is stable. This situation is common for elements with an odd atomic number. It is the only primordial aluminium isotope, i.e. the only one that has existed on Earth in its current form since the formation of the planet. Nearly all aluminium on Earth is present as this isotope, which makes it a mononuclidic element and means that its standard atomic weight is virtually the same as that of the isotope. This makes aluminium very useful in nuclear magnetic resonance (NMR), as its single stable isotope has a high NMR sensitivity. The standard atomic weight of aluminium is low in comparison with many other metals.
All other isotopes of aluminium are radioactive. The most stable of these is 26Al: while it was present along with stable 27Al in the interstellar medium from which the Solar System formed, having been produced by stellar nucleosynthesis as well, its half-life is only 717,000 years and therefore a detectable amount has not survived since the formation of the planet. However, minute traces of 26Al are produced from argon in the atmosphere by spallation caused by cosmic ray protons. The ratio of 26Al to 10Be has been used for radiodating of geological processes over 105 to 106 year time scales, in particular transport, deposition, sediment storage, burial times, and erosion. Most meteorite scientists believe that the energy released by the decay of 26Al was responsible for the melting and differentiation of some asteroids after their formation 4.55 billion years ago.
The remaining isotopes of aluminium, with mass numbers ranging from 22 to 43, all have half-lives well under an hour. Three metastable states are known, all with half-lives under a minute.
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904_2 | Electron shell
An aluminium atom has 13 electrons, arranged in an electron configuration of [Ne] 3s2 3p1, with three electrons beyond a stable noble gas configuration. Accordingly, the combined first three ionization energies of aluminium are far lower than the fourth ionization energy alone. Such an electron configuration is shared with the other well-characterized members of its group, boron, gallium, indium, and thallium; it is also expected for nihonium. Aluminium can relatively easily surrender its three outermost electrons in many chemical reactions (see below). The electronegativity of aluminium is 1.61 (Pauling scale).
A free aluminium atom has a radius of 143 pm. With the three outermost electrons removed, the radius shrinks to 39 pm for a 4-coordinated atom or 53.5 pm for a 6-coordinated atom. At standard temperature and pressure, aluminium atoms (when not affected by atoms of other elements) form a face-centered cubic crystal system bound by metallic bonding provided by atoms' outermost electrons; hence aluminium (at these conditions) is a metal. This crystal system is shared by many other metals, such as lead and copper; the size of a unit cell of aluminium is comparable to that of those other metals. The system, however, is not shared by the other members of its group; boron has ionization energies too high to allow metallization, thallium has a hexagonal close-packed structure, and gallium and indium have unusual structures that are not close-packed like those of aluminium and thallium. The few electrons that are available for metallic bonding in aluminium metal are a probable cause for it being soft with a low melting point and low electrical resistivity.
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904_3 | Bulk
Aluminium metal has an appearance ranging from silvery white to dull gray, depending on the surface roughness. A fresh film of aluminium serves as a good reflector (approximately 92%) of visible light and an excellent reflector (as much as 98%) of medium and far infrared radiation. Aluminium mirrors are the most reflective of all metal mirrors for the near ultraviolet and far infrared light, and one of the most reflective in the visible spectrum, nearly on par with silver, and the two therefore look similar. Aluminium is also good at reflecting solar radiation, although prolonged exposure to sunlight in air adds wear to the surface of the metal; this may be prevented if aluminium is anodized, which adds a protective layer of oxide on the surface.
The density of aluminium is 2.70 g/cm3, about 1/3 that of steel, much lower than other commonly encountered metals, making aluminium parts easily identifiable through their lightness. Aluminium's low density compared to most other metals arises from the fact that its nuclei are much lighter, while difference in the unit cell size does not compensate for this difference. The only lighter metals are the metals of groups 1 and 2, which apart from beryllium and magnesium are too reactive for structural use (and beryllium is very toxic). Aluminium is not as strong or stiff as steel, but the low density makes up for this in the aerospace industry and for many other applications where light weight and relatively high strength are crucial.
Pure aluminium is quite soft and lacking in strength. In most applications various aluminium alloys are used instead because of their higher strength and hardness. The yield strength of pure aluminium is 7–11 MPa, while aluminium alloys have yield strengths ranging from 200 MPa to 600 MPa. Aluminium is ductile, with a percent elongation of 50-70%, and malleable allowing it to be easily drawn and extruded. It is also easily machined and cast. | [
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904_4 | Aluminium is an excellent thermal and electrical conductor, having around 60% the conductivity of copper, both thermal and electrical, while having only 30% of copper's density. Aluminium is capable of superconductivity, with a superconducting critical temperature of 1.2 kelvin and a critical magnetic field of about 100 gauss (10 milliteslas). It is paramagnetic and thus essentially unaffected by static magnetic fields. The high electrical conductivity, however, means that it is strongly affected by alternating magnetic fields through the induction of eddy currents.
Chemistry
Aluminium combines characteristics of pre- and post-transition metals. Since it has few available electrons for metallic bonding, like its heavier group 13 congeners, it has the characteristic physical properties of a post-transition metal, with longer-than-expected interatomic distances. Furthermore, as Al3+ is a small and highly charged cation, it is strongly polarizing and bonding in aluminium compounds tends towards covalency; this behavior is similar to that of beryllium (Be2+), and the two display an example of a diagonal relationship.
The underlying core under aluminium's valence shell is that of the preceding noble gas, whereas those of its heavier congeners gallium, indium, thallium, and nihonium also include a filled d-subshell and in some cases a filled f-subshell. Hence, the inner electrons of aluminium shield the valence electrons almost completely, unlike those of aluminium's heavier congeners. As such, aluminium is the most electropositive metal in its group, and its hydroxide is in fact more basic than that of gallium. Aluminium also bears minor similarities to the metalloid boron in the same group: AlX3 compounds are valence isoelectronic to BX3 compounds (they have the same valence electronic structure), and both behave as Lewis acids and readily form adducts. Additionally, one of the main motifs of boron chemistry is regular icosahedral structures, and aluminium forms an important part of many icosahedral quasicrystal alloys, including the Al–Zn–Mg class. | [
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904_5 | Aluminium has a high chemical affinity to oxygen, which renders it suitable for use as a reducing agent in the thermite reaction. A fine powder of aluminium metal reacts explosively on contact with liquid oxygen; under normal conditions, however, aluminium forms a thin oxide layer (~5 nm at room temperature) that protects the metal from further corrosion by oxygen, water, or dilute acid, a process termed passivation. Because of its general resistance to corrosion, aluminium is one of the few metals that retains silvery reflectance in finely powdered form, making it an important component of silver-colored paints. Aluminium is not attacked by oxidizing acids because of its passivation. This allows aluminium to be used to store reagents such as nitric acid, concentrated sulfuric acid, and some organic acids.
In hot concentrated hydrochloric acid, aluminium reacts with water with evolution of hydrogen, and in aqueous sodium hydroxide or potassium hydroxide at room temperature to form aluminates—protective passivation under these conditions is negligible. Aqua regia also dissolves aluminium. Aluminium is corroded by dissolved chlorides, such as common sodium chloride, which is why household plumbing is never made from aluminium. The oxide layer on aluminium is also destroyed by contact with mercury due to amalgamation or with salts of some electropositive metals. As such, the strongest aluminium alloys are less corrosion-resistant due to galvanic reactions with alloyed copper, and aluminium's corrosion resistance is greatly reduced by aqueous salts, particularly in the presence of dissimilar metals.
Aluminium reacts with most nonmetals upon heating, forming compounds such as aluminium nitride (AlN), aluminium sulfide (Al2S3), and the aluminium halides (AlX3). It also forms a wide range of intermetallic compounds involving metals from every group on the periodic table.
Inorganic compounds
The vast majority of compounds, including all aluminium-containing minerals and all commercially significant aluminium compounds, feature aluminium in the oxidation state 3+. The coordination number of such compounds varies, but generally Al3+ is either six- or four-coordinate. Almost all compounds of aluminium(III) are colorless. | [
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904_6 | In aqueous solution, Al3+ exists as the hexaaqua cation [Al(H2O)6]3+, which has an approximate Ka of 10−5. Such solutions are acidic as this cation can act as a proton donor and progressively hydrolyze until a precipitate of aluminium hydroxide, Al(OH)3, forms. This is useful for clarification of water, as the precipitate nucleates on suspended particles in the water, hence removing them. Increasing the pH even further leads to the hydroxide dissolving again as aluminate, [Al(H2O)2(OH)4]−, is formed.
Aluminium hydroxide forms both salts and aluminates and dissolves in acid and alkali, as well as on fusion with acidic and basic oxides. This behavior of Al(OH)3 is termed amphoterism and is characteristic of weakly basic cations that form insoluble hydroxides and whose hydrated species can also donate their protons. One effect of this is that aluminium salts with weak acids are hydrolyzed in water to the aquated hydroxide and the corresponding nonmetal hydride: for example, aluminium sulfide yields hydrogen sulfide. However, some salts like aluminium carbonate exist in aqueous solution but are unstable as such; and only incomplete hydrolysis takes place for salts with strong acids, such as the halides, nitrate, and sulfate. For similar reasons, anhydrous aluminium salts cannot be made by heating their "hydrates": hydrated aluminium chloride is in fact not AlCl3·6H2O but [Al(H2O)6]Cl3, and the Al–O bonds are so strong that heating is not sufficient to break them and form Al–Cl bonds instead:
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904_7 | All four trihalides are well known. Unlike the structures of the three heavier trihalides, aluminium fluoride (AlF3) features six-coordinate aluminium, which explains its involatility and insolubility as well as high heat of formation. Each aluminium atom is surrounded by six fluorine atoms in a distorted octahedral arrangement, with each fluorine atom being shared between the corners of two octahedra. Such {AlF6} units also exist in complex fluorides such as cryolite, Na3AlF6. AlF3 melts at and is made by reaction of aluminium oxide with hydrogen fluoride gas at .
With heavier halides, the coordination numbers are lower. The other trihalides are dimeric or polymeric with tetrahedral four-coordinate aluminium centers. Aluminium trichloride (AlCl3) has a layered polymeric structure below its melting point of but transforms on melting to Al2Cl6 dimers. At higher temperatures those increasingly dissociate into trigonal planar AlCl3 monomers similar to the structure of BCl3. Aluminium tribromide and aluminium triiodide form Al2X6 dimers in all three phases and hence do not show such significant changes of properties upon phase change. These materials are prepared by treating aluminium metal with the halogen. The aluminium trihalides form many addition compounds or complexes; their Lewis acidic nature makes them useful as catalysts for the Friedel–Crafts reactions. Aluminium trichloride has major industrial uses involving this reaction, such as in the manufacture of anthraquinones and styrene; it is also often used as the precursor for many other aluminium compounds and as a reagent for converting nonmetal fluorides into the corresponding chlorides (a transhalogenation reaction). | [
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904_8 | Aluminium forms one stable oxide with the chemical formula Al2O3, commonly called alumina. It can be found in nature in the mineral corundum, α-alumina; there is also a γ-alumina phase. Its crystalline form, corundum, is very hard (Mohs hardness 9), has a high melting point of , has very low volatility, is chemically inert, and a good electrical insulator, it is often used in abrasives (such as toothpaste), as a refractory material, and in ceramics, as well as being the starting material for the electrolytic production of aluminium metal. Sapphire and ruby are impure corundum contaminated with trace amounts of other metals. The two main oxide-hydroxides, AlO(OH), are boehmite and diaspore. There are three main trihydroxides: bayerite, gibbsite, and nordstrandite, which differ in their crystalline structure (polymorphs). Many other intermediate and related structures are also known. Most are produced from ores by a variety of wet processes using acid and base. Heating the hydroxides leads to formation of corundum. These materials are of central importance to the production of aluminium and are themselves extremely useful. Some mixed oxide phases are also very useful, such as spinel (MgAl2O4), Na-β-alumina (NaAl11O17), and tricalcium aluminate (Ca3Al2O6, an important mineral phase in Portland cement). | [
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904_9 | The only stable chalcogenides under normal conditions are aluminium sulfide (Al2S3), selenide (Al2Se3), and telluride (Al2Te3). All three are prepared by direct reaction of their elements at about and quickly hydrolyze completely in water to yield aluminium hydroxide and the respective hydrogen chalcogenide. As aluminium is a small atom relative to these chalcogens, these have four-coordinate tetrahedral aluminium with various polymorphs having structures related to wurtzite, with two-thirds of the possible metal sites occupied either in an orderly (α) or random (β) fashion; the sulfide also has a γ form related to γ-alumina, and an unusual high-temperature hexagonal form where half the aluminium atoms have tetrahedral four-coordination and the other half have trigonal bipyramidal five-coordination.
Four pnictides – aluminium nitride (AlN), aluminium phosphide (AlP), aluminium arsenide (AlAs), and aluminium antimonide (AlSb) – are known. They are all III-V semiconductors isoelectronic to silicon and germanium, all of which but AlN have the zinc blende structure. All four can be made by high-temperature (and possibly high-pressure) direct reaction of their component elements.
Aluminium alloys well with most other metals (with the exception of most alkali metals and group 13 metals) and over 150 intermetallics with other metals are known. Preparation involves heating fixed metals together in certain proportion, followed by gradual cooling and annealing. Bonding in them is predominantly metallic and the crystal structure primarily depends on efficiency of packing. | [
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904_10 | There are few compounds with lower oxidation states. A few aluminium(I) compounds exist: AlF, AlCl, AlBr, and AlI exist in the gaseous phase when the respective trihalide is heated with aluminium, and at cryogenic temperatures. A stable derivative of aluminium monoiodide is the cyclic adduct formed with triethylamine, Al4I4(NEt3)4. Al2O and Al2S also exist but are very unstable. Very simple aluminium(II) compounds are invoked or observed in the reactions of Al metal with oxidants. For example, aluminium monoxide, AlO, has been detected in the gas phase after explosion and in stellar absorption spectra. More thoroughly investigated are compounds of the formula R4Al2 which contain an Al–Al bond and where R is a large organic ligand.
Organoaluminium compounds and related hydrides
A variety of compounds of empirical formula AlR3 and AlR1.5Cl1.5 exist. The aluminium trialkyls and triaryls are reactive, volatile, and colorless liquids or low-melting solids. They catch fire spontaneously in air and react with water, thus necessitating precautions when handling them. They often form dimers, unlike their boron analogues, but this tendency diminishes for branched-chain alkyls (e.g. Pri, Bui, Me3CCH2); for example, triisobutylaluminium exists as an equilibrium mixture of the monomer and dimer. These dimers, such as trimethylaluminium (Al2Me6), usually feature tetrahedral Al centers formed by dimerization with some alkyl group bridging between both aluminium atoms. They are hard acids and react readily with ligands, forming adducts. In industry, they are mostly used in alkene insertion reactions, as discovered by Karl Ziegler, most importantly in "growth reactions" that form long-chain unbranched primary alkenes and alcohols, and in the low-pressure polymerization of ethene and propene. There are also some heterocyclic and cluster organoaluminium compounds involving Al–N bonds. | [
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904_11 | The industrially most important aluminium hydride is lithium aluminium hydride (LiAlH4), which is used in as a reducing agent in organic chemistry. It can be produced from lithium hydride and aluminium trichloride. The simplest hydride, aluminium hydride or alane, is not as important. It is a polymer with the formula (AlH3)n, in contrast to the corresponding boron hydride that is a dimer with the formula (BH3)2.
Natural occurrence
Space
Aluminium's per-particle abundance in the Solar System is 3.15 ppm (parts per million). It is the twelfth most abundant of all elements and third most abundant among the elements that have odd atomic numbers, after hydrogen and nitrogen. The only stable isotope of aluminium, 27Al, is the eighteenth most abundant nucleus in the Universe. It is created almost entirely after fusion of carbon in massive stars that will later become Type II supernovas: this fusion creates 26Mg, which, upon capturing free protons and neutrons becomes aluminium. Some smaller quantities of 27Al are created in hydrogen burning shells of evolved stars, where 26Mg can capture free protons. Essentially all aluminium now in existence is 27Al. 26Al was present in the early Solar System with abundance of 0.005% relative to 27Al but its half-life of 728,000 years is too short for any original nuclei to survive; 26Al is therefore extinct. Unlike for 27Al, hydrogen burning is the primary source of 26Al, with the nuclide emerging after a nucleus of 25Mg catches a free proton. However, the trace quantities of 26Al that do exist are the most common gamma ray emitter in the interstellar gas; if the original 26Al were still present, gamma ray maps of the Milky Way would be brighter.
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904_12 | Earth
Overall, the Earth is about 1.59% aluminium by mass (seventh in abundance by mass). Aluminium occurs in greater proportion in the Earth's crust than in the Universe at large, because aluminium easily forms the oxide and becomes bound into rocks and stays in the Earth's crust, while less reactive metals sink to the core. In the Earth's crust, aluminium is the most abundant metallic element (8.23% by mass) and the third most abundant of all elements (after oxygen and silicon). A large number of silicates in the Earth's crust contain aluminium. In contrast, the Earth's mantle is only 2.38% aluminium by mass. Aluminium also occurs in seawater at a concentration of 2 μg/kg.
Because of its strong affinity for oxygen, aluminium is almost never found in the elemental state; instead it is found in oxides or silicates. Feldspars, the most common group of minerals in the Earth's crust, are aluminosilicates. Aluminium also occurs in the minerals beryl, cryolite, garnet, spinel, and turquoise. Impurities in Al2O3, such as chromium and iron, yield the gemstones ruby and sapphire, respectively. Native aluminium metal is extremely rare and can only be found as a minor phase in low oxygen fugacity environments, such as the interiors of certain volcanoes. Native aluminium has been reported in cold seeps in the northeastern continental slope of the South China Sea. It is possible that these deposits resulted from bacterial reduction of tetrahydroxoaluminate Al(OH)4−.
Although aluminium is a common and widespread element, not all aluminium minerals are economically viable sources of the metal. Almost all metallic aluminium is produced from the ore bauxite (AlOx(OH)3–2x). Bauxite occurs as a weathering product of low iron and silica bedrock in tropical climatic conditions. In 2017, most bauxite was mined in Australia, China, Guinea, and India.
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904_13 | History
The history of aluminium has been shaped by usage of alum. The first written record of alum, made by Greek historian Herodotus, dates back to the 5th century BCE. The ancients are known to have used alum as a dyeing mordant and for city defense. After the Crusades, alum, an indispensable good in the European fabric industry, was a subject of international commerce; it was imported to Europe from the eastern Mediterranean until the mid-15th century.
The nature of alum remained unknown. Around 1530, Swiss physician Paracelsus suggested alum was a salt of an earth of alum. In 1595, German doctor and chemist Andreas Libavius experimentally confirmed this. In 1722, German chemist Friedrich Hoffmann announced his belief that the base of alum was a distinct earth. In 1754, German chemist Andreas Sigismund Marggraf synthesized alumina by boiling clay in sulfuric acid and subsequently adding potash.
Attempts to produce aluminium metal date back to 1760. The first successful attempt, however, was completed in 1824 by Danish physicist and chemist Hans Christian Ørsted. He reacted anhydrous aluminium chloride with potassium amalgam, yielding a lump of metal looking similar to tin. He presented his results and demonstrated a sample of the new metal in 1825. In 1827, German chemist Friedrich Wöhler repeated Ørsted's experiments but did not identify any aluminium. (The reason for this inconsistency was only discovered in 1921.) He conducted a similar experiment in the same year by mixing anhydrous aluminium chloride with potassium and produced a powder of aluminium. In 1845, he was able to produce small pieces of the metal and described some physical properties of this metal. For many years thereafter, Wöhler was credited as the discoverer of aluminium.
As Wöhler's method could not yield great quantities of aluminium, the metal remained rare; its cost exceeded that of gold. The first industrial production of aluminium was established in 1856 by French chemist Henri Etienne Sainte-Claire Deville and companions. Deville had discovered that aluminium trichloride could be reduced by sodium, which was more convenient and less expensive than potassium, which Wöhler had used. Even then, aluminium was still not of great purity and produced aluminium differed in properties by sample. | [
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904_14 | The first industrial large-scale production method was independently developed in 1886 by French engineer Paul Héroult and American engineer Charles Martin Hall; it is now known as the Hall–Héroult process. The Hall–Héroult process converts alumina into metal. Austrian chemist Carl Joseph Bayer discovered a way of purifying bauxite to yield alumina, now known as the Bayer process, in 1889. Modern production of the aluminium metal is based on the Bayer and Hall–Héroult processes.
Prices of aluminium dropped and aluminium became widely used in jewelry, everyday items, eyeglass frames, optical instruments, tableware, and foil in the 1890s and early 20th century. Aluminium's ability to form hard yet light alloys with other metals provided the metal with many uses at the time. During World War I, major governments demanded large shipments of aluminium for light strong airframes; during World War II, demand by major governments for aviation was even higher.
By the mid-20th century, aluminium had become a part of everyday life and an essential component of housewares. In 1954, production of aluminium surpassed that of copper, historically second in production only to iron, making it the most produced non-ferrous metal. During the mid-20th century, aluminium emerged as a civil engineering material, with building applications in both basic construction and interior finish work, and increasingly being used in military engineering, for both airplanes and land armor vehicle engines. Earth's first artificial satellite, launched in 1957, consisted of two separate aluminium semi-spheres joined and all subsequent space vehicles have used aluminium to some extent. The aluminium can was invented in 1956 and employed as a storage for drinks in 1958.
Throughout the 20th century, the production of aluminium rose rapidly: while the world production of aluminium in 1900 was 6,800 metric tons, the annual production first exceeded 100,000 metric tons in 1916; 1,000,000 tons in 1941; 10,000,000 tons in 1971. In the 1970s, the increased demand for aluminium made it an exchange commodity; it entered the London Metal Exchange, the oldest industrial metal exchange in the world, in 1978. The output continued to grow: the annual production of aluminium exceeded 50,000,000 metric tons in 2013. | [
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904_15 | The real price for aluminium declined from $14,000 per metric ton in 1900 to $2,340 in 1948 (in 1998 United States dollars). Extraction and processing costs were lowered over technological progress and the scale of the economies. However, the need to exploit lower-grade poorer quality deposits and the use of fast increasing input costs (above all, energy) increased the net cost of aluminium; the real price began to grow in the 1970s with the rise of energy cost. Production moved from the industrialized countries to countries where production was cheaper. Production costs in the late 20th century changed because of advances in technology, lower energy prices, exchange rates of the United States dollar, and alumina prices. The BRIC countries' combined share in primary production and primary consumption grew substantially in the first decade of the 21st century. China is accumulating an especially large share of the world's production thanks to an abundance of resources, cheap energy, and governmental stimuli; it also increased its consumption share from 2% in 1972 to 40% in 2010. In the United States, Western Europe, and Japan, most aluminium was consumed in transportation, engineering, construction, and packaging. In 2021, prices for industrial metals such as aluminium have soared to near-record levels as energy shortages in China drive up costs for electricity.
Etymology
The names aluminium and aluminum are derived from the word alumine, an obsolete term for alumina, a naturally occurring oxide of aluminium. Alumine was borrowed from French, which in turn derived it from alumen, the classical Latin name for alum, the mineral from which it was collected. The Latin word alumen stems from the Proto-Indo-European root *alu- meaning "bitter" or "beer". | [
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904_16 | Coinage
British chemist Humphry Davy, who performed a number of experiments aimed to isolate the metal, is credited as the person who named the element. The first name proposed for the metal to be isolated from alum was alumium, which Davy suggested in an 1808 article on his electrochemical research, published in Philosophical Transactions of the Royal Society. It appeared that the name was coined from the English word alum and the Latin suffix -ium; however, it was customary at the time that the elements should have names originating in the Latin language, and as such, this name was not adopted universally. This name was criticized by contemporary chemists from France, Germany, and Sweden, who insisted the metal should be named for the oxide, alumina, from which it would be isolated. The English word name alum does not directly reference the Latin language, whereas alumine/alumina easily references the Latin word alumen (upon declension, alumen changes to alumin-).
One example was a writing in French by Swedish chemist Jöns Jacob Berzelius titled Essai sur la Nomenclature chimique, published in July 1811; in this essay, among other things, Berzelius used the name aluminium for the element that would be synthesized from alum. (Another article in the same journal issue also refers to the metal whose oxide forms the basis of sapphire as to aluminium.) A January 1811 summary of one of Davy's lectures at the Royal Society mentioned the name aluminium as a possibility. The following year, Davy published a chemistry textbook in which he used the spelling aluminum. Both spellings have coexisted since; however, their usage has split by region: aluminum is the primary spelling in the United States and Canada while aluminium is in the rest of the English-speaking world. | [
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904_17 | Spelling
In 1812, British scientist Thomas Young wrote an anonymous review of Davy's book, in which he proposed the name aluminium instead of aluminum, which he felt had a "less classical sound". This name did catch on: while the spelling was occasionally used in Britain, the American scientific language used from the start. Most scientists used throughout the world in the 19th century, and it was entrenched in many other European languages, such as French, German, or Dutch. In 1828, American lexicographer Noah Webster used exclusively the aluminum spelling in his American Dictionary of the English Language. In the 1830s, the spelling started to gain usage in the United States; by the 1860s, it had become the more common spelling there outside science. In 1892, Hall used the spelling in his advertising handbill for his new electrolytic method of producing the metal, despite his constant use of the spelling in all the patents he filed between 1886 and 1903. It remains unknown whether this spelling was introduced by mistake or intentionally; however, Hall preferred aluminum since its introduction because it resembled platinum, the name of a prestigious metal. By 1890, both spellings had been common in the U.S. overall, the spelling being slightly more common; by 1895, the situation had reversed; by 1900, aluminum had become twice as common as aluminium; during the following decade, the spelling dominated American usage. In 1925, the American Chemical Society adopted this spelling.
The International Union of Pure and Applied Chemistry (IUPAC) adopted aluminium as the standard international name for the element in 1990. In 1993, they recognized aluminum as an acceptable variant; the most recent 2005 edition of the IUPAC nomenclature of inorganic chemistry acknowledges this spelling as well. IUPAC official publications use the spelling as primary but list both where appropriate.
Production and refinement
The production of aluminium starts with the extraction of bauxite rock from the ground. The bauxite is processed and transformed using the Bayer process into alumina, which is then processed using the Hall–Héroult process, resulting in the final aluminium metal. | [
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904_18 | Aluminium production is highly energy-consuming, and so the producers tend to locate smelters in places where electric power is both plentiful and inexpensive. As of 2019, the world's largest smelters of aluminium are located in China, India, Russia, Canada, and the United Arab Emirates, while China is by far the top producer of aluminium with a world share of fifty-five percent.
According to the International Resource Panel's Metal Stocks in Society report, the global per capita stock of aluminium in use in society (i.e. in cars, buildings, electronics, etc.) is . Much of this is in more-developed countries ( per capita) rather than less-developed countries ( per capita).
Bayer process
Bauxite is converted to alumina by the Bayer process. Bauxite is blended for uniform composition and then is ground. The resulting slurry is mixed with a hot solution of sodium hydroxide; the mixture is then treated in a digester vessel at a pressure well above atmospheric, dissolving the aluminium hydroxide in bauxite while converting impurities into relatively insoluble compounds:
After this reaction, the slurry is at a temperature above its atmospheric boiling point. It is cooled by removing steam as pressure is reduced. The bauxite residue is separated from the solution and discarded. The solution, free of solids, is seeded with small crystals of aluminium hydroxide; this causes decomposition of the [Al(OH)4]− ions to aluminium hydroxide. After about half of aluminium has precipitated, the mixture is sent to classifiers. Small crystals of aluminium hydroxide are collected to serve as seeding agents; coarse particles are converted to alumina by heating; the excess solution is removed by evaporation, (if needed) purified, and recycled.
Hall–Héroult process
The conversion of alumina to aluminium metal is achieved by the Hall–Héroult process. In this energy-intensive process, a solution of alumina in a molten () mixture of cryolite (Na3AlF6) with calcium fluoride is electrolyzed to produce metallic aluminium. The liquid aluminium metal sinks to the bottom of the solution and is tapped off, and usually cast into large blocks called aluminium billets for further processing. | [
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904_19 | Anodes of the electrolysis cell are made of carbon—the most resistant material against fluoride corrosion—and either bake at the process or are prebaked. The former, also called Söderberg anodes, are less power-efficient and fumes released during baking are costly to collect, which is why they are being replaced by prebaked anodes even though they save the power, energy, and labor to prebake the cathodes. Carbon for anodes should be preferably pure so that neither aluminium nor the electrolyte is contaminated with ash. Despite carbon's resistivity against corrosion, it is still consumed at a rate of 0.4–0.5 kg per each kilogram of produced aluminium. Cathodes are made of anthracite; high purity for them is not required because impurities leach only very slowly. The cathode is consumed at a rate of 0.02–0.04 kg per each kilogram of produced aluminium. A cell is usually terminated after 2–6 years following a failure of the cathode.
The Hall–Heroult process produces aluminium with a purity of above 99%. Further purification can be done by the Hoopes process. This process involves the electrolysis of molten aluminium with a sodium, barium, and aluminium fluoride electrolyte. The resulting aluminium has a purity of 99.99%.
Electric power represents about 20 to 40% of the cost of producing aluminium, depending on the location of the smelter. Aluminium production consumes roughly 5% of electricity generated in the United States. Because of this, alternatives to the Hall–Héroult process have been researched, but none has turned out to be economically feasible.
Recycling
Recovery of the metal through recycling has become an important task of the aluminium industry. Recycling was a low-profile activity until the late 1960s, when the growing use of aluminium beverage cans brought it to public awareness. Recycling involves melting the scrap, a process that requires only 5% of the energy used to produce aluminium from ore, though a significant part (up to 15% of the input material) is lost as dross (ash-like oxide). An aluminium stack melter produces significantly less dross, with values reported below 1%. | [
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] |
904_20 | White dross from primary aluminium production and from secondary recycling operations still contains useful quantities of aluminium that can be extracted industrially. The process produces aluminium billets, together with a highly complex waste material. This waste is difficult to manage. It reacts with water, releasing a mixture of gases (including, among others, hydrogen, acetylene, and ammonia), which spontaneously ignites on contact with air; contact with damp air results in the release of copious quantities of ammonia gas. Despite these difficulties, the waste is used as a filler in asphalt and concrete.
Applications
Metal
The global production of aluminium in 2016 was 58.8 million metric tons. It exceeded that of any other metal except iron (1,231 million metric tons).
Aluminium is almost always alloyed, which markedly improves its mechanical properties, especially when tempered. For example, the common aluminium foils and beverage cans are alloys of 92% to 99% aluminium. The main alloying agents are copper, zinc, magnesium, manganese, and silicon (e.g., duralumin) with the levels of other metals in a few percent by weight. Aluminium, both wrought and cast, has been alloyed with: manganese, silicon, magnesium, copper and zinc among others. For example, the Kynal family of alloys was developed by the British chemical manufacturer Imperial Chemical Industries. | [
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904_21 | The major uses for aluminium metal are in:
Transportation (automobiles, aircraft, trucks, railway cars, marine vessels, bicycles, spacecraft, etc.). Aluminium is used because of its low density;
Packaging (cans, foil, frame, etc.). Aluminium is used because it is non-toxic (see below), non-adsorptive, and splinter-proof;
Building and construction (windows, doors, siding, building wire, sheathing, roofing, etc.). Since steel is cheaper, aluminium is used when lightness, corrosion resistance, or engineering features are important;
Electricity-related uses (conductor alloys, motors, and generators, transformers, capacitors, etc.). Aluminium is used because it is relatively cheap, highly conductive, has adequate mechanical strength and low density, and resists corrosion;
A wide range of household items, from cooking utensils to furniture. Low density, good appearance, ease of fabrication, and durability are the key factors of aluminium usage;
Machinery and equipment (processing equipment, pipes, tools). Aluminium is used because of its corrosion resistance, non-pyrophoricity, and mechanical strength.
Portable computer cases. Currently rarely used without alloying, but aluminium can be recycled and clean aluminium has residual market value: for example, the used beverage can (UBC) material was used to encase the electronic components of MacBook Air laptop, Pixel 5 smartphone or Summit Lite smartwatch.
Compounds
The great majority (about 90%) of aluminium oxide is converted to metallic aluminium. Being a very hard material (Mohs hardness 9), alumina is widely used as an abrasive; being extraordinarily chemically inert, it is useful in highly reactive environments such as high pressure sodium lamps. Aluminium oxide is commonly used as a catalyst for industrial processes; e.g. the Claus process to convert hydrogen sulfide to sulfur in refineries and to alkylate amines. Many industrial catalysts are supported by alumina, meaning that the expensive catalyst material is dispersed over a surface of the inert alumina. Another principal use is as a drying agent or absorbent. | [
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904_22 | Several sulfates of aluminium have industrial and commercial application. Aluminium sulfate (in its hydrate form) is produced on the annual scale of several millions of metric tons. About two-thirds is consumed in water treatment. The next major application is in the manufacture of paper. It is also used as a mordant in dyeing, in pickling seeds, deodorizing of mineral oils, in leather tanning, and in production of other aluminium compounds. Two kinds of alum, ammonium alum and potassium alum, were formerly used as mordants and in leather tanning, but their use has significantly declined following availability of high-purity aluminium sulfate. Anhydrous aluminium chloride is used as a catalyst in chemical and petrochemical industries, the dyeing industry, and in synthesis of various inorganic and organic compounds. Aluminium hydroxychlorides are used in purifying water, in the paper industry, and as antiperspirants. Sodium aluminate is used in treating water and as an accelerator of solidification of cement.
Many aluminium compounds have niche applications, for example:
Aluminium acetate in solution is used as an astringent.
Aluminium phosphate is used in the manufacture of glass, ceramic, pulp and paper products, cosmetics, paints, varnishes, and in dental cement.
Aluminium hydroxide is used as an antacid, and mordant; it is used also in water purification, the manufacture of glass and ceramics, and in the waterproofing of fabrics.
Lithium aluminium hydride is a powerful reducing agent used in organic chemistry.
Organoaluminiums are used as Lewis acids and co-catalysts.
Methylaluminoxane is a co-catalyst for Ziegler–Natta olefin polymerization to produce vinyl polymers such as polyethene.
Aqueous aluminium ions (such as aqueous aluminium sulfate) are used to treat against fish parasites such as Gyrodactylus salaris.
In many vaccines, certain aluminium salts serve as an immune adjuvant (immune response booster) to allow the protein in the vaccine to achieve sufficient potency as an immune stimulant.
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904_23 | Biology
Despite its widespread occurrence in the Earth's crust, aluminium has no known function in biology. At pH 6–9 (relevant for most natural waters), aluminium precipitates out of water as the hydroxide and is hence not available; most elements behaving this way have no biological role or are toxic. Aluminium salts are nontoxic. Aluminium sulfate has an LD50 of 6207 mg/kg (oral, mouse), which corresponds to 435 grams for an person, though lethality and neurotoxicity differ in their implications. Andrási et al. discovered "significantly higher Aluminum" content in some brain regions when necroscopies of subjects with Alzheimer disease were compared to subjects without. Aluminium chelates with glyphosate.
Toxicity
Aluminium is classified as a non-carcinogen by the United States Department of Health and Human Services. A review published in 1988 said that there was little evidence that normal exposure to aluminium presents a risk to healthy adult, and a 2014 multi-element toxicology review was unable to find deleterious effects of aluminium consumed in amounts not greater than 40 mg/day per kg of body mass. Most aluminium consumed will leave the body in feces; most of the small part of it that enters the bloodstream, will be excreted via urine; nevertheless some aluminium does pass the blood-brain barrier and is lodged preferentially in the brains of Alzheimer's patients. Evidence published in 1989 indicates that, for Alzheimer's patients, aluminium may act by electrostatically crosslinking proteins, thus down-regulating genes in the superior temporal gyrus.
Effects
Aluminium, although rarely, can cause vitamin D-resistant osteomalacia, erythropoietin-resistant microcytic anemia, and central nervous system alterations. People with kidney insufficiency are especially at a risk. Chronic ingestion of hydrated aluminium silicates (for excess gastric acidity control) may result in aluminium binding to intestinal contents and increased elimination of other metals, such as iron or zinc; sufficiently high doses (>50 g/day) can cause anemia. | [
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904_24 | During the 1988 Camelford water pollution incident people in Camelford had their drinking water contaminated with aluminium sulfate for several weeks. A final report into the incident in 2013 concluded it was unlikely that this had caused long-term health problems.
Aluminium has been suspected of being a possible cause of Alzheimer's disease, but research into this for over 40 years has found, , no good evidence of causal effect.
Aluminium increases estrogen-related gene expression in human breast cancer cells cultured in the laboratory. In very high doses, aluminium is associated with altered function of the blood–brain barrier. A small percentage of people have contact allergies to aluminium and experience itchy red rashes, headache, muscle pain, joint pain, poor memory, insomnia, depression, asthma, irritable bowel syndrome, or other symptoms upon contact with products containing aluminium.
Exposure to powdered aluminium or aluminium welding fumes can cause pulmonary fibrosis. Fine aluminium powder can ignite or explode, posing another workplace hazard.
Exposure routes
Food is the main source of aluminium. Drinking water contains more aluminium than solid food; however, aluminium in food may be absorbed more than aluminium from water. Major sources of human oral exposure to aluminium include food (due to its use in food additives, food and beverage packaging, and cooking utensils), drinking water (due to its use in municipal water treatment), and aluminium-containing medications (particularly antacid/antiulcer and buffered aspirin formulations). Dietary exposure in Europeans averages to 0.2–1.5 mg/kg/week but can be as high as 2.3 mg/kg/week. Higher exposure levels of aluminium are mostly limited to miners, aluminium production workers, and dialysis patients.
Consumption of antacids, antiperspirants, vaccines, and cosmetics provide possible routes of exposure. Consumption of acidic foods or liquids with aluminium enhances aluminium absorption, and maltol has been shown to increase the accumulation of aluminium in nerve and bone tissues.
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904_25 | Treatment
In case of suspected sudden intake of a large amount of aluminium, the only treatment is deferoxamine mesylate which may be given to help eliminate aluminium from the body by chelation. However, this should be applied with caution as this reduces not only aluminium body levels, but also those of other metals such as copper or iron.
Environmental effects
High levels of aluminium occur near mining sites; small amounts of aluminium are released to the environment at the coal-fired power plants or incinerators. Aluminium in the air is washed out by the rain or normally settles down but small particles of aluminium remain in the air for a long time.
Acidic precipitation is the main natural factor to mobilize aluminium from natural sources and the main reason for the environmental effects of aluminium; however, the main factor of presence of aluminium in salt and freshwater are the industrial processes that also release aluminium into air.
In water, aluminium acts as a toxiс agent on gill-breathing animals such as fish when the water is acidic, in which aluminium may precipitate on gills, which causes loss of plasma- and hemolymph ions leading to osmoregulatory failure. Organic complexes of aluminium may be easily absorbed and interfere with metabolism in mammals and birds, even though this rarely happens in practice.
Aluminium is primary among the factors that reduce plant growth on acidic soils. Although it is generally harmless to plant growth in pH-neutral soils, in acid soils the concentration of toxic Al3+ cations increases and disturbs root growth and function. Wheat has developed a tolerance to aluminium, releasing organic compounds that bind to harmful aluminium cations. Sorghum is believed to have the same tolerance mechanism.
Aluminium production possesses its own challenges to the environment on each step of the production process. The major challenge is the greenhouse gas emissions. These gases result from electrical consumption of the smelters and the byproducts of processing. The most potent of these gases are perfluorocarbons from the smelting process. Released sulfur dioxide is one of the primary precursors of acid rain. | [
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904_26 | A Spanish scientific report from 2001 claimed that the fungus Geotrichum candidum consumes the aluminium in compact discs. Other reports all refer back to that report and there is no supporting original research. Better documented, the bacterium Pseudomonas aeruginosa and the fungus Cladosporium resinae are commonly detected in aircraft fuel tanks that use kerosene-based fuels (not avgas), and laboratory cultures can degrade aluminium. However, these life forms do not directly attack or consume the aluminium; rather, the metal is corroded by microbe waste products.
See also
Aluminium granules
Aluminium joining
Aluminium–air battery
Panel edge staining
Quantum clock
Notes
References
Bibliography
Further reading
Mimi Sheller, Aluminum Dream: The Making of Light Modernity. Cambridge, Mass.: Massachusetts Institute of Technology Press, 2014.
External links
Aluminium at The Periodic Table of Videos (University of Nottingham)
Toxic Substances Portal – Aluminum – from the Agency for Toxic Substances and Disease Registry, United States Department of Health and Human Services
CDC – NIOSH Pocket Guide to Chemical Hazards – Aluminum
World production of primary aluminium, by country
Price history of aluminum, according to the IMF
History of Aluminium – from the website of the International Aluminium Institute
Emedicine – Aluminium
Aluminium
Electrical conductors
Pyrotechnic fuels
Airship technology
Chemical elements
Post-transition metals
Reducing agents
E-number additives
Native element minerals
Chemical elements with face-centered cubic structure | [
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] |
905_0 | Advanced Chemistry is a German hip hop group from Heidelberg, a scenic city in Baden-Württemberg, South Germany. Advanced Chemistry was founded in 1987 by Toni L, Linguist, Gee-One, DJ Mike MD (Mike Dippon) and MC Torch. Each member of the group holds German citizenship, and Toni L, Linguist, and Torch are of Italian, Ghanaian, and Haitian backgrounds, respectively.
Influenced by North American socially conscious rap and the Native tongues movement, Advanced Chemistry is regarded as one of the main pioneers in German hip hop. They were one of the first groups to rap in German (although their name is in English). Furthermore, their songs tackled controversial social and political issues, distinguishing them from early German hip hop group "Die Fantastischen Vier" (The Fantastic Four), which had a more light-hearted, playful, party image.
Career
Advanced Chemistry frequently rapped about their lives and experiences as children of immigrants, exposing the marginalization experienced by most ethnic minorities in Germany, and the feelings of frustration and resentment that being denied a German identity can cause. The song "Fremd im eigenen Land" (Foreign in your own nation) was released by Advanced Chemistry in November 1992. The single became a staple in the German hip hop scene. It made a strong statement about the status of immigrants throughout Germany, as the group was composed of multi-national and multi-racial members. The video shows several members brandishing their German passports as a demonstration of their German citizenship to skeptical and unaccepting 'ethnic' Germans.
This idea of national identity is important, as many rap artists in Germany have been of foreign origin. These so-called Gastarbeiter (guest workers) children saw breakdance, graffiti, rap music, and hip hop culture as a means of expressing themselves. Since the release of "Fremd im eigenen Land", many other German-language rappers have also tried to confront anti-immigrant ideas and develop themes of citizenship. However, though many ethnic minority youth in Germany find these German identity themes appealing, others view the desire of immigrants to be seen as German negatively, and they have actively sought to revive and recreate concepts of identity in connection to traditional ethnic origins.
Advanced Chemistry helped to found the German chapter of the Zulu nation. | [
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905_1 | Advanced Chemistry helped to found the German chapter of the Zulu nation.
The rivalry between Advanced Chemistry and Die Fantastischen Vier has served to highlight a dichotomy in the routes that hip hop has taken in becoming a part of the German soundscape. While Die Fantastischen Vier may be said to view hip hop primarily as an aesthetic art form, Advanced Chemistry understand hip hop as being inextricably linked to the social and political circumstances under which it is created. For Advanced Chemistry, hip hop is a “vehicle of general human emancipation,”. In their undertaking of social and political issues, the band introduced the term "Afro-German" into the context of German hip hop, and the theme of race is highlighted in much of their music.
With the release of the single “Fremd im eigenen Land”, Advanced Chemistry separated itself from the rest of the rap being produced in Germany. This single was the first of its kind to go beyond simply imitating US rap and addressed the current issues of the time. Fremd im eigenen Land which translates to “foreign in my own country” dealt with the widespread racism that non-white German citizens faced. This change from simple imitation to political commentary was the start of German identification with rap. The sound of “Fremd im eigenen Land” was influenced by the 'wall of noise' created by Public Enemy's producers, The Bomb Squad. | [
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] |
905_2 | After the reunification of Germany, an abundance of anti-immigrant sentiment emerged, as well as attacks on the homes of refugees in the early 1990s. Advanced Chemistry came to prominence in the wake of these actions because of their pro-multicultural society stance in their music. Advanced Chemistry's attitudes revolve around their attempts to create a distinct "Germanness" in hip hop, as opposed to imitating American hip hop as other groups had done. Torch has said, "What the Americans do is exotic for us because we don't live like they do. What they do seems to be more interesting and newer. But not for me. For me it's more exciting to experience my fellow Germans in new contexts...For me, it's interesting to see what the kids try to do that's different from what I know." Advanced Chemistry were the first to use the term "Afro-German" in a hip hop context. This was part of the pro-immigrant political message they sent via their music. | [
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905_3 | While Advanced Chemistry's use of the German language in their rap allows them to make claims to authenticity and true German heritage, bolstering pro-immigration sentiment, their style can also be problematic for immigrant notions of any real ethnic roots. Indeed, part of the Turkish ethnic minority of Frankfurt views Advanced Chemistry's appeal to the German image as a "symbolic betrayal of the right of ethnic minorities to 'roots' or to any expression of cultural heritage." In this sense, their rap represents a complex social discourse internal to the German soundscape in which they attempt to negotiate immigrant assimilation into a xenophobic German culture with the maintenance of their own separate cultural traditions. It is quite possibly the feelings of alienation from the pure-blooded German demographic that drive Advanced Chemistry to attack nationalistic ideologies by asserting their "Germanness" as a group composed primarily of ethnic others. The response to this pseudo-German authenticity can be seen in what Andy Bennett refers to as "alternative forms of local hip hop culture which actively seek to rediscover and, in many cases, reconstruct notions of identity tied to cultural roots." These alternative local hip hop cultures include oriental hip hop, the members of which cling to their Turkish heritage and are confused by Advanced Chemistry's elicitation of a German identity politics to which they technically do not belong. This cultural binary illustrates that rap has taken different routes in Germany and that, even among an already isolated immigrant population, there is still disunity and, especially, disagreement on the relative importance of assimilation versus cultural defiance. According to German hip hop enthusiast 9@home, Advanced Chemistry is part of a "hip-hop movement [which] took a clear stance for the minorities and against the [marginalization] of immigrants who...might be German on paper, but not in real life," which speaks to the group's hope of actually being recognized as German citizens and not foreigners, despite their various other ethnic and cultural ties. | [
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] |
905_4 | Influences
Advanced Chemistry's work was rooted in German history and the country's specific political realities. However, they also drew inspiration from African-American hip-hop acts like A Tribe Called Quest and Public Enemy, who had helped bring a soulful sound and political consciousness to American hip-hop. One member, Torch, later explicitly listed his references on his solo song "Als (When I Was in School):" "My favorite subject, which was quickly discovered poetry in load Poets, awakens the intellect or policy at Chuck D I'll never forget the lyrics by Public Enemy." Torch goes on to list other American rappers like Biz Markie, Big Daddy Kane and Dr. Dre as influences.
Discography
1992 - "Fremd im eigenen Land" (12"/MCD, MZEE)
1993 - "Welcher Pfad führt zur Geschichte" (12"/MCD, MZEE)
1994 - "Operation § 3" (12"/MCD)
1994 - "Dir fehlt der Funk!" (12"/MCD)
1995 - Advanced Chemistry (2xLP/CD)
External links
Official Website of MC Torch
Website of Toni L
Official Website of Linguist
Official Website DJ Mike MD (Mike Dippon)
Website of 360° Records
Bibliography
El-Tayeb, Fatima “‘If You Cannot Pronounce My Name, You Can Just Call Me
Pride.’ Afro-German Activism, Gender, and Hip Hop,” Gender & History15/3(2003):459-485.
Felbert, Oliver von. “Die Unbestechlichen.” Spex (March 1993): 50–53.
Weheliye, Alexander G. Phonographies:Grooves in Sonic Afro-Modernity, Duke University Press, 2005.
References
German hip hop groups | [
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909_0 | The Anglican Communion is the third largest Christian communion after the Roman Catholic and Eastern Orthodox churches. Founded in 1867 in London, the communion has more than 85 million members within the Church of England and other autocephalous national and regional churches in full communion. The traditional origins of Anglican doctrine are summarised in the Thirty-nine Articles (1571). The Archbishop of Canterbury (currently Justin Welby) in England acts as a focus of unity, recognised as primus inter pares ("first among equals"), but does not exercise authority in Anglican provinces outside of the Church of England. Most, but not all, member churches of the communion are the historic national or regional Anglican churches.
The Anglican Communion was officially and formally organised and recognised as such at the Lambeth Conference in 1867 in London under the leadership of Charles Longley, Archbishop of Canterbury. The churches of the Anglican Communion consider themselves to be part of the one, holy, catholic and apostolic church, and to be both catholic and reformed. As in the Church of England itself, the Anglican Communion includes the broad spectrum of beliefs and liturgical practises found in the Evangelical, Central and Anglo-Catholic traditions of Anglicanism. Each national or regional church is fully independent, retaining its own legislative process and episcopal polity under the leadership of local primates. For some adherents, Anglicanism represents a non-papal Catholicism, for others a form of Protestantism though without a guiding figure such as Luther, Knox, Calvin, Zwingli or Wesley, or for yet others a combination of the two.
Most of its members live in the Anglosphere of former British territories. Full participation in the sacramental life of each church is available to all communicant members. Because of their historical link to England (ecclesia anglicana means "English church"), some of the member churches are known as "Anglican", such as the Anglican Church of Canada. Others, for example the Church of Ireland and the Scottish and American Episcopal churches, have official names that do not include "Anglican". Additionally, some churches which use the name "Anglican" are not part of the communion.
Ecclesiology, polity and ethos | [
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909_1 | Ecclesiology, polity and ethos
The Anglican Communion has no official legal existence nor any governing structure which might exercise authority over the member churches. There is an Anglican Communion Office in London, under the aegis of the Archbishop of Canterbury, but it only serves in a supporting and organisational role. The communion is held together by a shared history, expressed in its ecclesiology, polity and ethos, and also by participation in international consultative bodies.
Three elements have been important in holding the communion together: first, the shared ecclesial structure of the component churches, manifested in an episcopal polity maintained through the apostolic succession of bishops and synodical government; second, the principle of belief expressed in worship, investing importance in approved prayer books and their rubrics; and third, the historical documents and the writings of early Anglican divines that have influenced the ethos of the communion.
Originally, the Church of England was self-contained and relied for its unity and identity on its own history, its traditional legal and episcopal structure, and its status as an established church of the state. As such, Anglicanism was from the outset a movement with an explicitly episcopal polity, a characteristic that has been vital in maintaining the unity of the communion by conveying the episcopate's role in manifesting visible catholicity and ecumenism.
Early in its development following the English Reformation, Anglicanism developed a vernacular prayer book, called the Book of Common Prayer. Unlike other traditions, Anglicanism has never been governed by a magisterium nor by appeal to one founding theologian, nor by an extra-credal summary of doctrine (such as the Westminster Confession of the Presbyterian churches). Instead, Anglicans have typically appealed to the Book of Common Prayer (1662) and its offshoots as a guide to Anglican theology and practise. This has had the effect of inculcating in Anglican identity and confession the principle of lex orandi, lex credendi ("the law of praying [is] the law of believing"). | [
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909_2 | Protracted conflict through the 17th century, with radical Protestants on the one hand and Roman Catholics who recognised the primacy of the Pope on the other, resulted in an association of churches that was both deliberately vague about doctrinal principles, yet bold in developing parameters of acceptable deviation. These parameters were most clearly articulated in the various rubrics of the successive prayer books, as well as the Thirty-Nine Articles of Religion (1563). These articles have historically shaped and continue to direct the ethos of the communion, an ethos reinforced by its interpretation and expansion by such influential early theologians such as Richard Hooker, Lancelot Andrewes and John Cosin.
With the expansion of the British Empire the growth of Anglicanism outside Great Britain and Ireland, the communion sought to establish new vehicles of unity. The first major expressions of this were the Lambeth Conferences of the communion's bishops, first convened in 1867 by Charles Longley, the Archbishop of Canterbury. From the beginning, these were not intended to displace the autonomy of the emerging provinces of the communion, but to "discuss matters of practical interest, and pronounce what we deem expedient in resolutions which may serve as safe guides to future action".
Chicago Lambeth Quadrilateral
One of the enduringly influential early resolutions of the conference was the so-called Chicago-Lambeth Quadrilateral of 1888. Its intent was to provide the basis for discussions of reunion with the Roman Catholic and Orthodox churches, but it had the ancillary effect of establishing parameters of Anglican identity. It establishes four principles with these words:
Instruments of communion
As mentioned above, the Anglican Communion has no international juridical organisation. The Archbishop of Canterbury's role is strictly symbolic and unifying and the communion's three international bodies are consultative and collaborative, their resolutions having no legal effect on the autonomous provinces of the communion. Taken together, however, the four do function as "instruments of communion", since all churches of the communion participate in them. In order of antiquity, they are: | [
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909_3 | The Archbishop of Canterbury functions as the spiritual head of the communion. The archbishop is the focus of unity, since no church claims membership in the Communion without being in communion with him. The present archbishop is Justin Welby.
The Lambeth Conference (first held in 1867) is the oldest international consultation. It is a forum for bishops of the communion to reinforce unity and collegiality through manifesting the episcopate, to discuss matters of mutual concern, and to pass resolutions intended to act as guideposts. It is held roughly every 10 years and invitation is by the Archbishop of Canterbury.
The Anglican Consultative Council (first met in 1971) was created by a 1968 Lambeth Conference resolution, and meets usually at three-yearly intervals. The council consists of representative bishops, other clergy and laity chosen by the 38 provinces. The body has a permanent secretariat, the Anglican Communion Office, of which the Archbishop of Canterbury is president.
The Primates' Meeting (first met in 1979) is the most recent manifestation of international consultation and deliberation, having been first convened by Archbishop Donald Coggan as a forum for "leisurely thought, prayer and deep consultation".
Since there is no binding authority in the Anglican Communion, these international bodies are a vehicle for consultation and persuasion. In recent times, persuasion has tipped over into debates over conformity in certain areas of doctrine, discipline, worship and ethics. The most notable example has been the objection of many provinces of the communion (particularly in Africa and Asia) to the changing acceptance of LGBTQ+ individuals in the North American churches (e.g., by blessing same-sex unions and ordaining and consecrating same-sex relationships) and to the process by which changes were undertaken. (See Anglican realignment)
Those who objected condemned these actions as unscriptural, unilateral, and without the agreement of the communion prior to these steps being taken. In response, the American Episcopal Church and the Anglican Church of Canada answered that the actions had been undertaken after lengthy scriptural and theological reflection, legally in accordance with their own canons and constitutions and after extensive consultation with the provinces of the communion. | [
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909_4 | The Primates' Meeting voted to request the two churches to withdraw their delegates from the 2005 meeting of the Anglican Consultative Council. Canada and the United States decided to attend the meeting but without exercising their right to vote. They have not been expelled or suspended, since there is no mechanism in this voluntary association to suspend or expel an independent province of the communion. Since membership is based on a province's communion with Canterbury, expulsion would require the Archbishop of Canterbury's refusal to be in communion with the affected jurisdictions. In line with the suggestion of the Windsor Report, Rowan Williams (the then Archbishop of Canterbury) established a working group to examine the feasibility of an Anglican covenant which would articulate the conditions for communion in some fashion.
Organisation
Provinces
The Anglican communion consists of forty-one autonomous provinces each with its own primate and governing structure. These provinces may take the form of national churches (such as in Canada, Uganda, or Japan) or a collection of nations (such as the West Indies, Central Africa, or Southeast Asia).
Extraprovincial churches
In addition to the forty-one provinces, there are five extraprovincial churches under the metropolitical authority of the Archbishop of Canterbury.
Former provinces
New provinces in formation
At its Autumn 2020 meeting the provincial standing committee of the Church of Southern Africa approved a plan to form the dioceses in Mozambique and Angola into a separate autonomous province of the Anglican Communion, to be named the Anglican Church of Mozambique and Angola (IAMA). The plans were also outlined to the Mozambique and Angola Anglican Association (MANNA) at its September 2020 annual general meeting. The new province is Portuguese-speaking, and consists of twelve dioceses (four in Angola, and eight in Mozambique). The twelve proposed new dioceses have been defined and named, and each has a "Task Force Committee" working towards its establishment as a diocese. The plan received the consent of the bishops and diocesan synods of all four existing dioceses in the two nations, and was submitted to the Anglican Consultative Council.
In September 2020 the Archbishop of Canterbury announced that he had asked the bishops of the Church of Ceylon to begin planning for the formation of an autonomous province of Ceylon, so as to end his current position as Metropolitan of the two dioceses in that country.
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909_5 | Churches in full communion
In addition to other member churches, the churches of the Anglican Communion are in full communion with the Old Catholic churches of the Union of Utrecht and the Scandinavian Lutheran churches of the Porvoo Communion in Europe, the India-based Malankara Mar Thoma Syrian and Malabar Independent Syrian churches and the Philippine Independent Church, also known as the Aglipayan Church.
History
The Anglican Communion traces much of its growth to the older mission organisations of the Church of England such as the Society for Promoting Christian Knowledge (founded 1698), the Society for the Propagation of the Gospel in Foreign Parts (founded 1701) and the Church Missionary Society (founded 1799). The Church of England (which until the 20th century included the Church in Wales) initially separated from the Roman Catholic Church in 1534 in the reign of Henry VIII, reunited in 1555 under Mary I and then separated again in 1570 under Elizabeth I (the Roman Catholic Church excommunicated Elizabeth I in 1570 in response to the Act of Supremacy 1559).
The Church of England has always thought of itself not as a new foundation but rather as a reformed continuation of the ancient "English Church" (Ecclesia Anglicana) and a reassertion of that church's rights. As such it was a distinctly national phenomenon. The Church of Scotland was formed as a separate church from the Roman Catholic Church as a result of the Scottish Reformation in 1560 and the later formation of the Scottish Episcopal Church began in 1582 in the reign of James VI over disagreements about the role of bishops.
The oldest-surviving Anglican church building outside the British Isles (Britain and Ireland) is St Peter's Church in St. George's, Bermuda, established in 1612 (though the actual building had to be rebuilt several times over the following century). This is also the oldest surviving non-Roman Catholic church in the New World. It remained part of the Church of England until 1978 when the Anglican Church of Bermuda separated. The Church of England was the established church not only in England, but in its trans-Oceanic colonies. | [
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909_6 | Thus the only member churches of the present Anglican Communion existing by the mid-18th century were the Church of England, its closely linked sister church the Church of Ireland (which also separated from Roman Catholicism under Henry VIII) and the Scottish Episcopal Church which for parts of the 17th and 18th centuries was partially underground (it was suspected of Jacobite sympathies).
Global spread of Anglicanism
The enormous expansion in the 18th and 19th centuries of the British Empire brought Anglicanism along with it. At first all these colonial churches were under the jurisdiction of the bishop of London. After the American Revolution, the parishes in the newly independent country found it necessary to break formally from a church whose supreme governor was (and remains) the British monarch. Thus they formed their own dioceses and national church, the Episcopal Church in the United States of America, in a mostly amicable separation.
At about the same time, in the colonies which remained linked to the crown, the Church of England began to appoint colonial bishops. In 1787, a bishop of Nova Scotia was appointed with a jurisdiction over all of British North America; in time several more colleagues were appointed to other cities in present-day Canada. In 1814, a bishop of Calcutta was made; in 1824 the first bishop was sent to the West Indies and in 1836 to Australia. By 1840 there were still only ten colonial bishops for the Church of England; but even this small beginning greatly facilitated the growth of Anglicanism around the world. In 1841, a "Colonial Bishoprics Council" was set up and soon many more dioceses were created.
In time, it became natural to group these into provinces and a metropolitan bishop was appointed for each province. Although it had at first been somewhat established in many colonies, in 1861 it was ruled that, except where specifically established, the Church of England had just the same legal position as any other church. Thus a colonial bishop and colonial diocese was by nature quite a different thing from their counterparts back home. In time bishops came to be appointed locally rather than from England and eventually national synods began to pass ecclesiastical legislation independent of England. | [
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909_7 | A crucial step in the development of the modern communion was the idea of the Lambeth Conferences (discussed above). These conferences demonstrated that the bishops of disparate churches could manifest the unity of the church in their episcopal collegiality despite the absence of universal legal ties. Some bishops were initially reluctant to attend, fearing that the meeting would declare itself a council with power to legislate for the church; but it agreed to pass only advisory resolutions. These Lambeth Conferences have been held roughly every 10 years since 1878 (the second such conference) and remain the most visible coming-together of the whole Communion.
The Lambeth Conference of 1998 included what has been seen by Philip Jenkins and others as a "watershed in global Christianity". The 1998 Lambeth Conference considered the issue of the theology of same-sex attraction in relation to human sexuality. At this 1998 conference for the first time in centuries the Christians of developing regions, especially, Africa, Asia, and Latin America, prevailed over the bishops of more prosperous countries (many from the US, Canada, and the UK) who supported a redefinition of Anglican doctrine. Seen in this light 1998 is a date that marked the shift from a West-dominated Christianity to one wherein the growing churches of the two-thirds world are predominant, but the gay bishop controversy in subsequent years led to the reassertion of Western dominance, this time of the liberal variety.
Ecumenical relations
Historic episcopate
The churches of the Anglican Communion have traditionally held that ordination in the historic episcopate is a core element in the validity of clerical ordinations. The Roman Catholic Church, however, does not recognise Anglican orders (see Apostolicae curae). Some Eastern Orthodox churches have issued statements to the effect that Anglican orders could be accepted, yet have still reordained former Anglican clergy; other Eastern Orthodox churches have rejected Anglican orders altogether. Orthodox bishop Kallistos Ware explains this apparent discrepancy as follows:
Controversies
One effect of the Communion's dispersed authority has been the conflicts arising over divergent practices and doctrines in parts of the Communion. Disputes that had been confined to the Church of England could be dealt with legislatively in that realm, but as the Communion spread out into new nations and disparate cultures, such controversies multiplied and intensified. These controversies have generally been of two types: liturgical and social. | [
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909_8 | Anglo-Catholicism
The first such controversy of note concerned that of the growing influence of the Catholic Revival manifested in the Tractarian and so-called Ritualist controversies of the late nineteenth and early twentieth centuries. This controversy produced the Free Church of England and, in the United States and Canada, the Reformed Episcopal Church.
Social changes
Later, rapid social change and the dissipation of British cultural hegemony over its former colonies contributed to disputes over the role of women, the parameters of marriage and divorce, and the practices of contraception and abortion. In the late 1970s, the Continuing Anglican movement produced a number of new church bodies in opposition to women's ordination, prayer book changes, and the new understandings concerning marriage.
Same-sex unions and LGBT clergy
More recently, disagreements over homosexuality have strained the unity of the communion as well as its relationships with other Christian denominations, leading to another round of withdrawals from the Anglican Communion. Some churches were founded outside the Anglican Communion in the late 20th and early 21st centuries, largely in opposition to the ordination of openly homosexual bishops and other clergy and are usually referred to as belonging to the Anglican realignment movement, or else as "orthodox" Anglicans. These disagreements were especially noted when the Episcopal Church (US) consecrated an openly gay bishop in a same-sex relationship, Gene Robinson, in 2003, which led some Episcopalians to defect and found the Anglican Church in North America (ACNA); then, the debate re-ignited when the Church of England agreed to allow clergy to enter into same-sex civil partnerships, as long as they remained celibate, in 2005. The Church of Nigeria opposed the Episcopal Church's decision as well as the Church of England's approval for celibate civil partnerships. | [
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909_9 | "The more liberal provinces that are open to changing Church doctrine on marriage in order to allow for same-sex unions include Brazil, Canada, New Zealand, Scotland, South India, South Africa, the US and Wales". The Church of England does not allow same-gender marriages or blessing rites, but does permit special prayer services for same-sex couples following a civil marriage or partnership. The Church of England also permits clergy to enter into same-sex civil partnerships. The Church of Ireland has no official position on civil unions, and one senior cleric has entered into a same-sex civil partnership. The Church of Ireland recognised that it will "treat civil partners the same as spouses". The Anglican Church of Australia does not have an official position on homosexuality.
The conservative Anglican churches, encouraging the realignment movement, are more concentrated in the Global South. For example, the Anglican Church of Kenya, the Church of Nigeria and the Church of Uganda have opposed homosexuality. GAFCON, a fellowship of conservative Anglican churches, has appointed "missionary bishops" in response to the disagreements with the perceived liberalisation in the Anglican churches in North America and Europe.
Debates about social theology and ethics have occurred at the same time as debates on prayer book revision and the acceptable grounds for achieving full communion with non-Anglican churches.
See also
Acts of Supremacy
English Reformation
Dissolution of the Monasteries
Ritualism in the Church of England
Apostolicae curae
Affirming Catholicism
Anglican ministry
Anglo-Catholicism
British Israelism
Church Society
Church's Ministry Among Jewish People
Compass rose
Evangelical Anglicanism
Flag of the Anglican Communion
Liberal Anglo-Catholicism
List of conservative evangelical Anglican churches in England
List of heroes of the Christian Church in the Anglican Communion
List of the largest Protestant bodies
Reform (Anglican)
Anglican Use
Notes
References
Citations
Sources
Further reading
Buchanan, Colin. Historical Dictionary of Anglicanism (2nd ed. 2015) excerpt
Hebert, A. G. The Form of the Church. London: Faber and Faber, 1944.
Wild, John. What is the Anglican Communion?, in series, The Advent Papers. Cincinnati, Ohio: Forward Movement Publications, [196-]. Note.: Expresses the "Anglo-Catholic" viewpoint.
External links
Anglicans Online
Project Canterbury Anglican historical documents from around the world
Brief description and history of the Anglican Communion 1997 article from the Anglican Communion Office | [
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909_10 | 1867 establishments in England
Religious organizations established in 1867
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910_0 | Arne Kaijser (born 1950) is a professor emeritus of history of technology at the KTH Royal Institute of Technology in Stockholm, and a former president of the Society for the History of Technology.
Kaijser has published two books in Swedish: Stadens ljus. Etableringen av de första svenska gasverken and I fädrens spår. Den svenska infrastrukturens historiska utveckling och framtida utmaningar, and has co-edited several anthologies. Kaijser is a member of the Royal Swedish Academy of Engineering Sciences since 2007 and also a member of the editorial board of two scientific journals: Journal of Urban Technology and Centaurus. Lately, he has been occupied with the history of Large Technical Systems.
References
External links
Homepage
Extended homepage
1950 births
Living people
Swedish historians
KTH Royal Institute of Technology faculty
Members of the Royal Swedish Academy of Engineering Sciences
Historians of science
Historians of technology
Linköping University alumni | [
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911_0 | An archipelago ( ), sometimes called an island group or island chain, is a chain, cluster, or collection of islands, or sometimes a sea containing a small number of scattered islands.
Examples of archipelagos include: the Indonesian Archipelago, the Andaman and Nicobar Islands, the Lakshadweep Islands, the Galápagos Islands, the Japanese Archipelago, the Philippine Archipelago, the Maldives, the Balearic Isles, the Bahamas, the Aegean Islands, the Hawaiian Islands, the Canary Islands, Malta, the Azores, the Canadian Arctic Archipelago, the British Isles, the islands of the Archipelago Sea, and Shetland. They are sometimes defined by political boundaries. The Gulf archipelago off the north-eastern Pacific coast forms part of a larger archipelago that geographically includes Washington state's San Juan Islands. While the Gulf archipelago and San Juan Islands are geographically related, they are not technically included in the same archipelago due to manmade geopolitical borders.
Etymology
The word archipelago is derived from the Ancient Greek ἄρχι-(arkhi-, "chief") and πέλαγος (pélagos, "sea") through the Italian arcipelago. In antiquity, "Archipelago" (from medieval Greek *ἀρχιπέλαγος and Latin ) was the proper name for the Aegean Sea. Later, usage shifted to refer to the Aegean Islands (since the sea has a large number of islands).
Geographic types
Archipelagos may be found isolated in large amounts of water or neighbouring a large land mass. For example, Scotland has more than 700 islands surrounding its mainland which form an archipelago.
Archipelagos are often volcanic, forming along island arcs generated by subduction zones or hotspots, but may also be the result of erosion, deposition, and land elevation. Depending on their geological origin, islands forming archipelagos can be referred to as oceanic islands, continental fragments, and continental islands.
Oceanic islands
Oceanic islands are mainly of volcanic origin, and widely separated from any adjacent continent. The Hawaiian Islands and Easter Island in the Pacific, and Île Amsterdam in the south Indian Ocean are examples.
Continental fragments
Continental fragments correspond to land masses that have separated from a continental mass due to tectonic displacement. The Farallon Islands off the coast of California are an example.
Continental archipelagos | [
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] |
911_1 | Continental archipelagos
Sets of islands formed close to the coast of a continent are considered continental archipelagos when they form part of the same continental shelf, when those islands are above-water extensions of the shelf. The islands of the Inside Passage off the coast of British Columbia and the Canadian Arctic Archipelago are examples.
Artificial archipelagos
Artificial archipelagos have been created in various countries for different purposes. Palm Islands and the World Islands off Dubai were or are being created for leisure and tourism purposes. Marker Wadden in the Netherlands is being built as a conservation area for birds and other wildlife.
Further examples
The largest archipelagic state in the world by area, and by population, is Indonesia.
See also
Island arc
List of landforms
List of archipelagos by number of islands
List of archipelagos
Archipelagic state
List of islands
Aquapelago
References
External links
30 Most Incredible Island Archipelagos
Coastal and oceanic landforms
Oceanographical terminology | [
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914_0 | An author is the creator or originator of any written work such as a book or play, and is also considered a writer or poet. More broadly defined, an author is "the person who originated or gave existence to anything" and whose authorship determines responsibility for what was created.
Legal significance of authorship
Typically, the first owner of a copyright is the person who created the work, i.e. the author. If more than one person created the work, then a case of joint authorship can be made provided some criteria are met. In the copyright laws of various jurisdictions, there is a necessity for little flexibility regarding what constitutes authorship. The United States Copyright Office, for example, defines copyright as "a form of protection provided by the laws of the United States (title 17, U.S. Code) to authors of 'original works of authorship.'"
Holding the title of "author" over any "literary, dramatic, musical, artistic, [or] certain other intellectual works" gives rights to this person, the owner of the copyright, especially the exclusive right to engage in or authorize any production or distribution of their work. Any person or entity wishing to use intellectual property held under copyright must receive permission from the copyright holder to use this work, and often will be asked to pay for the use of copyrighted material. After a fixed amount of time, the copyright expires on intellectual work and it enters the public domain, where it can be used without limit. Copyright laws in many jurisdictions – mostly following the lead of the United States, in which the entertainment and publishing industries have very strong lobbying power – have been amended repeatedly since their inception, to extend the length of this fixed period where the work is exclusively controlled by the copyright holder. However, copyright is merely the legal reassurance that one owns their work. Technically, someone owns their work from the time it's created. A notable aspect of authorship emerges with copyright in that, in many jurisdictions, it can be passed down to another upon one's death. The person who inherits the copyright is not the author, but enjoys the same legal benefits. | [
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914_1 | Questions arise as to the application of copyright law. How does it, for example, apply to the complex issue of fan fiction? If the media agency responsible for the authorized production allows material from fans, what is the limit before legal constraints from actors, music, and other considerations, come into play? Additionally, how does copyright apply to fan-generated stories for books? What powers do the original authors, as well as the publishers, have in regulating or even stopping the fan fiction? This particular sort of case also illustrates how complex intellectual property law can be, since such fiction may also involved trademark law (e.g. for names of characters in media franchises), likeness rights (such as for actors, or even entirely fictional entities), fair use rights held by the public (including the right to parody or satirize), and many other interacting complications.
Authors may portion out different rights they hold to different parties, at different times, and for different purposes or uses, such as the right to adapt a plot into a film, but only with different character names, because the characters have already been optioned by another company for a television series or a video game. An author may also not have rights when working under contract that they would otherwise have, such as when creating a work for hire (e.g., hired to write a city tour guide by a municipal government that totally owns the copyright to the finished work), or when writing material using intellectual property owned by others (such as when writing a novel or screenplay that is a new installment in an already established media franchise).
Philosophical views of the nature of authorship
In literary theory, critics find complications in the term author beyond what constitutes authorship in a legal setting. In the wake of postmodern literature, critics such as Roland Barthes and Michel Foucault have examined the role and relevance of authorship to the meaning or interpretation of a text. | [
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914_2 | Barthes challenges the idea that a text can be attributed to any single author. He writes, in his essay "Death of the Author" (1968), that "it is language which speaks, not the author." The words and language of a text itself determine and expose meaning for Barthes, and not someone possessing legal responsibility for the process of its production. Every line of written text is a mere reflection of references from any of a multitude of traditions, or, as Barthes puts it, "the text is a tissue of quotations drawn from the innumerable centres of culture"; it is never original. With this, the perspective of the author is removed from the text, and the limits formerly imposed by the idea of one authorial voice, one ultimate and universal meaning, are destroyed. The explanation and meaning of a work does not have to be sought in the one who produced it, "as if it were always in the end, through the more or less transparent allegory of the fiction, the voice of a single person, the author 'confiding' in us." The psyche, culture, fanaticism of an author can be disregarded when interpreting a text, because the words are rich enough themselves with all of the traditions of language. To expose meanings in a written work without appealing to the celebrity of an author, their tastes, passions, vices, is, to Barthes, to allow language to speak, rather than author.
Michel Foucault argues in his essay "What is an author?" (1969) that all authors are writers, but not all writers are authors. He states that "a private letter may have a signatory—it does not have an author." For a reader to assign the title of author upon any written work is to attribute certain standards upon the text which, for Foucault, are working in conjunction with the idea of "the author function." Foucault's author function is the idea that an author exists only as a function of a written work, a part of its structure, but not necessarily part of the interpretive process. The author's name "indicates the status of the discourse within a society and culture," and at one time was used as an anchor for interpreting a text, a practice which Barthes would argue is not a particularly relevant or valid endeavour. | [
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914_3 | Expanding upon Foucault's position, Alexander Nehamas writes that Foucault suggests "an author [...] is whoever can be understood to have produced a particular text as we interpret it," not necessarily who penned the text. It is this distinction between producing a written work and producing the interpretation or meaning in a written work that both Barthes and Foucault are interested in. Foucault warns of the risks of keeping the author's name in mind during interpretation, because it could affect the value and meaning with which one handles an interpretation.
Literary critics Barthes and Foucault suggest that readers should not rely on or look for the notion of one overarching voice when interpreting a written work, because of the complications inherent with a writer's title of "author." They warn of the dangers interpretations could suffer from when associating the subject of inherently meaningful words and language with the personality of one authorial voice. Instead, readers should allow a text to be interpreted in terms of the language as "author."
Relationship with publisher
Self-publishing
Self-publishing, self-publishing, independent publishing, or artisanal publishing is the "publication of any book, album or other media by its author without the involvement of a traditional publisher. It is the modern equivalent to traditional publishing."
Types
Unless a book is to be sold directly from the author to the public, an ISBN is required to uniquely identify the title. ISBN is a global standard used for all titles worldwide. Most self-publishing companies either provide their own ISBN to a title or can provide direction; it may be in the best interest of the self-published author to retain ownership of ISBN and copyright instead of using a number owned by a vanity press. A separate ISBN is needed for each edition of the book.
Electronic (e-book) publishing | [
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914_4 | Electronic (e-book) publishing
There are a variety of book formats and tools that can be used to create them. Because it is possible to create e-books with no up-front or per-book costs, this is a popular option for self-publishers. E-book publishing platforms include Pronoun, Smashwords, Blurb, Amazon Kindle Direct Publishing, CinnamonTeal Publishing, Papyrus Editor, ebook leap, Bookbaby, Pubit, Lulu, Llumina Press, and CreateSpace. E-book formats include epub, mobi, and PDF, among others.
Print-on-demand
Print-on-demand (POD) publishing refers to the ability to print high-quality books as needed. For self-published books, this is often a more economical option than conducting a print run of hundreds or thousands of books. Many companies, such as Createspace (owned by Amazon.com), Outskirts Press, Blurb, Lulu, Llumina Press, ReadersMagnet, and iUniverse, allow printing single books at per-book costs not much higher than those paid by publishing companies for large print runs.
Traditional publishing
With commissioned publishing, the publisher makes all the publication arrangements and the author covers all expenses.
The author of a work may receive a percentage calculated on a wholesale or a specific price or a fixed amount on each book sold. Publishers, at times, reduced the risk of this type of arrangement, by agreeing only to pay this after a certain number of copies had sold. In Canada, this practice occurred during the 1890s, but was not commonplace until the 1920s. Established and successful authors may receive advance payments, set against future royalties, but this is no longer common practice. Most independent publishers pay royalties as a percentage of net receipts – how net receipts are calculated varies from publisher to publisher. Under this arrangement, the author does not pay anything towards the expense of publication. The costs and financial risk are all carried by the publisher, who will then take the greatest percentage of the receipts. See Compensation for more.
Vanity publishing
This type of publisher normally charges a flat fee for arranging publication, offers a platform for selling, and then takes a percentage of the sale of every copy of a book. The author receives the rest of the money made. | [
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914_5 | Relationship with editor
The relationship between the author and the editor, often the author's only liaison to the publishing company, is often characterized as the site of tension. For the author to reach their audience, often through publication, the work usually must attract the attention of the editor. The idea of the author as the sole meaning-maker of necessity changes to include the influences of the editor and the publisher in order to engage the audience in writing as a social act. There are three principal areas covered by editors – Proofing (checking the Grammar and spelling, looking for typing errors), Story (potentially an area of deep angst for both author and publisher), and Layout (the setting of the final proof ready for publishing often requires minor text changes so a layout editor is required to ensure that these do not alter the sense of the text).
Pierre Bourdieu's essay "The Field of Cultural Production" depicts the publishing industry as a "space of literary or artistic position-takings," also called the "field of struggles," which is defined by the tension and movement inherent among the various positions in the field. Bourdieu claims that the "field of position-takings [...] is not the product of coherence-seeking intention or objective consensus," meaning that an industry characterized by position-takings is not one of harmony and neutrality. In particular for the writer, their authorship in their work makes their work part of their identity, and there is much at stake personally over the negotiation of authority over that identity. However, it is the editor who has "the power to impose the dominant definition of the writer and therefore to delimit the population of those entitled to take part in the struggle to define the writer". As "cultural investors," publishers rely on the editor position to identify a good investment in "cultural capital" which may grow to yield economic capital across all positions.
According to the studies of James Curran, the system of shared values among editors in Britain has generated a pressure among authors to write to fit the editors' expectations, removing the focus from the reader-audience and putting a strain on the relationship between authors and editors and on writing as a social act. Even the book review by the editors has more significance than the readership's reception.
Compensation
Authors rely on advance fees, royalty payments, adaptation of work to a screenplay, and fees collected from giving speeches. | [
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914_6 | A standard contract for an author will usually include provision for payment in the form of an advance and royalties. An advance is a lump sum paid in advance of publication. An advance must be earned out before royalties are payable. An advance may be paid in two lump sums: the first payment on contract signing, and the second on delivery of the completed manuscript or on publication.
Royalty payment is the sum paid to authors for each copy of a book sold and is traditionally around 10-12%, but self-published authors can earn about 40% – 60% royalties per each book sale. An author's contract may specify, for example, that they will earn 10% of the retail price of each book sold. Some contracts specify a scale of royalties payable (for example, where royalties start at 10% for the first 10,000 sales, but then increase to a higher percentage rate at higher sale thresholds).
An author's book must earn the advance before any further royalties are paid. For example, if an author is paid a modest advance of $2000, and their royalty rate is 10% of a book priced at $20 – that is, $2 per book – the book will need to sell 1000 copies before any further payment will be made. Publishers typically withhold payment of a percentage of royalties earned against returns.
In some countries, authors also earn income from a government scheme such as the ELR (educational lending right) and PLR (public lending right) schemes in Australia. Under these schemes, authors are paid a fee for the number of copies of their books in educational and/or public libraries.
These days, many authors supplement their income from book sales with public speaking engagements, school visits, residencies, grants, and teaching positions.
Ghostwriters, technical writers, and textbooks writers are typically paid in a different way: usually a set fee or a per word rate rather than on a percentage of sales.
In the year 2016, according to the U.S. Bureau of Labor Statistics, nearly 130,000 people worked in the U.S. as authors making an average of $61,240 per year.
See also
Academic authorship
Auteur
Authors' editor
Distributive writing
Lead author
List of novelists
Lists of poets
Lists of writers
Novelist
Professional writing
References
Writing occupations
Literary criticism | [
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915_0 | Andrey Andreyevich Markov (14 June 1856 – 20 July 1922) was a Russian mathematician best known for his work on stochastic processes. A primary subject of his research later became known as Markov chains or Markov processes.
Markov and his younger brother Vladimir Andreevich Markov (1871–1897) proved the Markov brothers' inequality.
His son, another Andrey Andreyevich Markov (1903–1979), was also a notable mathematician, making contributions to constructive mathematics and recursive function theory.
Biography
Andrey Markov was born on 14 June 1856 in Russia. He attended the St. Petersburg Grammar School, where some teachers saw him as a rebellious student. In his academics he performed poorly in most subjects other than mathematics. Later in life he attended Saint Petersburg Imperial University (now Saint Petersburg State University). among his teachers were Yulian Sokhotski (differential calculus, higher algebra), Konstantin Posse (analytic geometry), Yegor Zolotarev (integral calculus), Pafnuty Chebyshev (number theory and probability theory), Aleksandr Korkin (ordinary and partial differential equations), Mikhail Okatov (mechanism theory), Osip Somov (mechanics), and Nikolai Budajev (descriptive and higher geometry). He completed his studies at the university and was later asked if he would like to stay and have a career as a Mathematician. He later taught at high schools and continued his own mathematical studies. In this time he found a practical use for his mathematical skills. He figured out that he could use chains to model the alliteration of vowels and consonants in Russian literature. He also contributed to many other mathematical aspects in his time. He died at age 66 on 20 July 1922.
Timeline
In 1877, Markov was awarded a gold medal for his outstanding solution of the problem
About Integration of Differential Equations by Continued Fractions with an Application to the Equation .
During the following year, he passed the candidate's examinations, and he remained at the university to prepare for a lecturer's position.
In April 1880, Markov defended his master's thesis "On the Binary Square Forms with Positive Determinant", which was directed by Aleksandr Korkin and Yegor Zolotarev. Four years later in 1884, he defended his doctoral thesis titled "On Certain Applications of the Algebraic Continuous Fractions". | [
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] |
915_1 | His pedagogical work began after the defense of his master's thesis in autumn 1880. As a privatdozent he lectured on differential and integral calculus. Later he lectured alternately on "introduction to analysis", probability theory (succeeding Chebyshev, who had left the university in 1882) and the calculus of differences. From 1895 through 1905 he also lectured in differential calculus.
One year after the defense of his doctoral thesis, Markov was appointed extraordinary professor (1886) and in the same year he was elected adjunct to the Academy of Sciences. In 1890, after the death of Viktor Bunyakovsky, Markov became an extraordinary member of the academy. His promotion to an ordinary professor of St. Petersburg University followed in the fall of 1894.
In 1896, Markov was elected an ordinary member of the academy as the successor of Chebyshev. In 1905, he was appointed merited professor and was granted the right to retire, which he did immediately. Until 1910, however, he continued to lecture in the calculus of differences.
In connection with student riots in 1908, professors and lecturers of St. Petersburg University were ordered to monitor their students. Markov refused to accept this decree, and he wrote an explanation in which he declined to be an "agent of the governance". Markov was removed from further teaching duties at St. Petersburg University, and hence he decided to retire from the university.
Markov was an atheist. In 1912, he protested Leo Tolstoy's excommunication from the Russian Orthodox Church by requesting his own excommunication. The Church complied with his request.
In 1913, the council of St. Petersburg elected nine scientists honorary members of the university. Markov was among them, but his election was not affirmed by the minister of education. The affirmation only occurred four years later, after the February Revolution in 1917. Markov then resumed his teaching activities and lectured on probability theory and the calculus of differences until his death in 1922.
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] |
915_2 | See also
List of things named after Andrey Markov
Chebyshev–Markov–Stieltjes inequalities
Gauss–Markov theorem
Gauss–Markov process
Hidden Markov model
Markov blanket
Markov chain
Markov decision process
Markov's inequality
Markov brothers' inequality
Markov information source
Markov network
Markov number
Markov property
Markov process
Stochastic matrix (also known as Markov matrix)
Subjunctive possibility
Notes
References
Further reading
А. А. Марков. "Распространение закона больших чисел на величины, зависящие друг от друга". "Известия Физико-математического общества при Казанском университете", 2-я серия, том 15, с. 135–156, 1906.
A. A. Markov. "Extension of the limit theorems of probability theory to a sum of variables connected in a chain". reprinted in Appendix B of: R. Howard. Dynamic Probabilistic Systems, volume 1: Markov Chains. John Wiley and Sons, 1971.
External links
Markov, Andrei Andreyevich
Markov, Andrei Andreyevich
19th-century Russian mathematicians
20th-century Russian mathematicians
Russian atheists
Former Russian Orthodox Christians
Probability theorists
Saint Petersburg State University alumni
Full members of the Saint Petersburg Academy of Sciences
Full Members of the Russian Academy of Sciences (1917–1925)
People from Ryazan
Russian statisticians | [
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921_0 | Angst is fear or anxiety (anguish is its Latinate equivalent, and the words anxious and anxiety are of similar origin). The dictionary definition for angst is a feeling of anxiety, apprehension, or insecurity.
Etymology
The word angst was introduced into English from the Danish, Norwegian, and Dutch word and the German word . It is attested since the 19th century in English translations of the works of Kierkegaard and Freud. It is used in English to describe an intense feeling of apprehension, anxiety, or inner turmoil.
In other languages (with words from the Latin for "fear" or "panic"), the derived words differ in meaning; for example, as in the French and . The word angst has existed since the 8th century, from the Proto-Indo-European root , "restraint" from which Old High German developed. It is pre-cognate with the Latin , "tensity, tightness" and , "choking, clogging"; compare to the Ancient Greek () "strangle".
Existentialist angst
In existentialist philosophy, the term angst carries a specific conceptual meaning. The use of the term was first attributed to Danish philosopher Søren Kierkegaard (1813–1855). In The Concept of Anxiety (also known as The Concept of Dread, depending on the translation), Kierkegaard used the word Angest (in common Danish, angst, meaning "dread" or "anxiety") to describe a profound and deep-seated condition. Where non-human animals are guided solely by instinct, said Kierkegaard, human beings enjoy a freedom of choice that we find both appealing and terrifying. It is the anxiety of understanding of being free when considering undefined possibilities of one's life and the immense responsibility of having the power of choice over them. Kierkegaard's concept of angst reappeared in the works of existentialist philosophers who followed, such as Friedrich Nietzsche, Jean-Paul Sartre, and Martin Heidegger, each of whom developed the idea further in individual ways. While Kierkegaard's angst referred mainly to ambiguous feelings about moral freedom within a religious personal belief system, later existentialists discussed conflicts of personal principles, cultural norms, and existential despair. | [
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921_1 | Music
Existential angst makes its appearance in classical musical composition in the early twentieth century as a result of both philosophical developments and as a reflection of the war-torn times. Notable composers whose works are often linked with the concept include Gustav Mahler, Richard Strauss (operas Elektra and Salome), Claude-Achille Debussy (opera Pelleas et Melisande, ballet Jeux, other works), Jean Sibelius (especially the Fourth Symphony), Arnold Schoenberg (A Survivor from Warsaw, other works), Alban Berg, Francis Poulenc (opera Dialogues of the Carmelites), Dmitri Shostakovich (opera Lady Macbeth of the Mtsensk District, symphonies and chamber music), Béla Bartók (opera Bluebeard's Castle, other works), and Krzysztof Penderecki (especially Threnody to the Victims of Hiroshima).
Angst began to be discussed in reference to popular music in the mid- to late 1950s amid widespread concerns over international tensions and nuclear proliferation. Jeff Nuttall's book Bomb Culture (1968) traced angst in popular culture to Hiroshima. Dread was expressed in works of folk rock such as Bob Dylan's "Masters of War" (1963) and "A Hard Rain's a-Gonna Fall". The term often makes an appearance in reference to punk rock, grunge, nu metal, and works of emo where expressions of melancholy, existential despair, or nihilism predominate.
See also
References
External links
Anxiety
Emotions
Existentialist concepts | [
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922_0 | Anxiety is an emotion characterized by an unpleasant state of inner turmoil and includes subjectively unpleasant feelings of dread over anticipated events. It is often accompanied by nervous behavior such as pacing back and forth, somatic complaints, and rumination.
Anxiety is a feeling of uneasiness and worry, usually generalized and unfocused as an overreaction to a situation that is only subjectively seen as menacing. It is often accompanied by muscular tension, restlessness, fatigue, inability to catch one's breath, tightness in the abdominal region, and problems in concentration. Anxiety is closely related to fear, which is a response to a real or perceived immediate threat; anxiety involves the expectation of future threat including dread. People facing anxiety may withdraw from situations which have provoked anxiety in the past.
Though anxiety is a normal human response, when excessive or persisting beyond developmentally appropriate periods it may be diagnosed as an anxiety disorder. There are multiple forms of anxiety disorder (such as Generalized Anxiety Disorder and Obsessive Compulsive Disorder) with specific clinical definitions. Part of the definition of an anxiety disorder, which distinguishes it from every day anxiety, is that it is persistent, typically lasting 6 months or more, although the criterion for duration is intended as a general guide with allowance for some degree of flexibility and is sometimes of shorter duration in children.
Anxiety vs. fear
Anxiety is distinguished from fear, which is an appropriate cognitive and emotional response to a perceived threat. Anxiety is related to the specific behaviors of fight-or-flight responses, defensive behavior or escape. There is a false presumption that often circulates that anxiety only occurs in situations perceived as uncontrollable or unavoidable, but this is not always so. David Barlow defines anxiety as "a future-oriented mood state in which one is not ready or prepared to attempt to cope with upcoming negative events," and that it is a distinction between future and present dangers which divides anxiety and fear. Another description of anxiety is agony, dread, terror, or even apprehension. In positive psychology, anxiety is described as the mental state that results from a difficult challenge for which the subject has insufficient coping skills. | [
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922_1 | Fear and anxiety can be differentiated into four domains: (1) duration of emotional experience, (2) temporal focus, (3) specificity of the threat, and (4) motivated direction. Fear is short-lived, present-focused, geared towards a specific threat, and facilitating escape from threat. On the other hand, anxiety is long-acting, future-focused, broadly focused towards a diffuse threat, and promoting excessive caution while approaching a potential threat and interferes with constructive coping.
Joseph E. LeDoux and Lisa Feldman Barrett have both sought to separate automatic threat responses from additional associated cognitive activity within anxiety.
Symptoms
Anxiety can be experienced with long, drawn-out daily symptoms that reduce quality of life, known as chronic (or generalized) anxiety, or it can be experienced in short spurts with sporadic, stressful panic attacks, known as acute anxiety. Symptoms of anxiety can range in number, intensity, and frequency, depending on the person. While almost everyone has experienced anxiety at some point in their lives, most do not develop long-term problems with anxiety.
Anxiety may cause psychiatric and physiological symptoms.
The risk of anxiety leading to depression could possibly even lead to an individual harming themselves, which is why there are many 24-hour suicide prevention hotlines.
The behavioral effects of anxiety may include withdrawal from situations which have provoked anxiety or negative feelings in the past. Other effects may include changes in sleeping patterns, changes in habits, increase or decrease in food intake, and increased motor tension (such as foot tapping).
The emotional effects of anxiety may include "feelings of apprehension or dread, trouble concentrating, feeling tense or jumpy, anticipating the worst, irritability, restlessness, watching (and waiting) for signs (and occurrences) of danger, and, feeling like your mind's gone blank" as well as "nightmares/bad dreams, obsessions about sensations, déjà vu, a trapped-in-your-mind feeling, and feeling like everything is scary." It may include a vague experience and feeling of helplessness. | [
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922_2 | The cognitive effects of anxiety may include thoughts about suspected dangers, such as fear of dying: "You may ... fear that the chest pains are a deadly heart attack or that the shooting pains in your head are the result of a tumor or an aneurysm. You feel an intense fear when you think of dying, or you may think of it more often than normal, or can't get it out of your mind."
The physiological symptoms of anxiety may include:
Neurological, as headache, paresthesias, fasciculations, vertigo, or presyncope.
Digestive, as abdominal pain, nausea, diarrhea, indigestion, dry mouth, or bolus. Stress hormones released in an anxious state have an impact on bowel function and can manifest physical symptoms that may contribute to or exacerbate IBS.
Respiratory, as shortness of breath or sighing breathing.
Cardiac, as palpitations, tachycardia, or chest pain.
Muscular, as fatigue, tremors, or tetany.
Cutaneous, as perspiration, or itchy skin.
Uro-genital, as frequent urination, urinary urgency, dyspareunia, or impotence, chronic pelvic pain syndrome.
Types
There are various types of anxiety. Existential anxiety can occur when a person faces angst, an existential crisis, or nihilistic feelings. People can also face mathematical anxiety, somatic anxiety, stage fright, or test anxiety. Social anxiety refers to a fear of rejection and negative evaluation (being judged) by other people.
Existential
The philosopher Søren Kierkegaard, in The Concept of Anxiety (1844), described anxiety or dread associated with the "dizziness of freedom" and suggested the possibility for positive resolution of anxiety through the self-conscious exercise of responsibility and choosing. In Art and Artist (1932), the psychologist Otto Rank wrote that the psychological trauma of birth was the pre-eminent human symbol of existential anxiety and encompasses the creative person's simultaneous fear of – and desire for – separation, individuation, and differentiation. | [
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922_3 | The theologian Paul Tillich characterized existential anxiety as "the state in which a being is aware of its possible nonbeing" and he listed three categories for the nonbeing and resulting anxiety: ontic (fate and death), moral (guilt and condemnation), and spiritual (emptiness and meaninglessness). According to Tillich, the last of these three types of existential anxiety, i.e. spiritual anxiety, is predominant in modern times while the others were predominant in earlier periods. Tillich argues that this anxiety can be accepted as part of the human condition or it can be resisted but with negative consequences. In its pathological form, spiritual anxiety may tend to "drive the person toward the creation of certitude in systems of meaning which are supported by tradition and authority" even though such "undoubted certitude is not built on the rock of reality".
According to Viktor Frankl, the author of Man's Search for Meaning, when a person is faced with extreme mortal dangers, the most basic of all human wishes is to find a meaning of life to combat the "trauma of nonbeing" as death is near.
Depending on the source of the threat, psychoanalytic theory distinguishes the following types of anxiety:
realistic
neurotic
moral
Test and performance
According to Yerkes-Dodson law, an optimal level of arousal is necessary to best complete a task such as an exam, performance, or competitive event. However, when the anxiety or level of arousal exceeds that optimum, the result is a decline in performance.
Test anxiety is the uneasiness, apprehension, or nervousness felt by students who have a fear of failing an exam. Students who have test anxiety may experience any of the following: the association of grades with personal worth; fear of embarrassment by a teacher; fear of alienation from parents or friends; time pressures; or feeling a loss of control. Sweating, dizziness, headaches, racing heartbeats, nausea, fidgeting, uncontrollable crying or laughing and drumming on a desk are all common. Because test anxiety hinges on fear of negative evaluation, debate exists as to whether test anxiety is itself a unique anxiety disorder or whether it is a specific type of social phobia. The DSM-IV classifies test anxiety as a type of social phobia. | [
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922_4 | While the term "test anxiety" refers specifically to students, many workers share the same experience with regard to their career or profession. The fear of failing at a task and being negatively evaluated for failure can have a similarly negative effect on the adult. Management of test anxiety focuses on achieving relaxation and developing mechanisms to manage anxiety.
Stranger, social, and intergroup anxiety
Humans generally require social acceptance and thus sometimes dread the disapproval of others. Apprehension of being judged by others may cause anxiety in social environments.
Anxiety during social interactions, particularly between strangers, is common among young people. It may persist into adulthood and become social anxiety or social phobia. "Stranger anxiety" in small children is not considered a phobia. In adults, an excessive fear of other people is not a developmentally common stage; it is called social anxiety. According to Cutting, social phobics do not fear the crowd but the fact that they may be judged negatively.
Social anxiety varies in degree and severity. For some people, it is characterized by experiencing discomfort or awkwardness during physical social contact (e.g. embracing, shaking hands, etc.), while in other cases it can lead to a fear of interacting with unfamiliar people altogether. Those suffering from this condition may restrict their lifestyles to accommodate the anxiety, minimizing social interaction whenever possible. Social anxiety also forms a core aspect of certain personality disorders, including avoidant personality disorder.
To the extent that a person is fearful of social encounters with unfamiliar others, some people may experience anxiety particularly during interactions with outgroup members, or people who share different group memberships (i.e., by race, ethnicity, class, gender, etc.). Depending on the nature of the antecedent relations, cognitions, and situational factors, intergroup contact may be stressful and lead to feelings of anxiety. This apprehension or fear of contact with outgroup members is often called interracial or intergroup anxiety. | [
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922_5 | As is the case with the more generalized forms of social anxiety, intergroup anxiety has behavioral, cognitive, and affective effects. For instance, increases in schematic processing and simplified information processing can occur when anxiety is high. Indeed, such is consistent with related work on attentional bias in implicit memory. Additionally recent research has found that implicit racial evaluations (i.e. automatic prejudiced attitudes) can be amplified during intergroup interaction. Negative experiences have been illustrated in producing not only negative expectations, but also avoidant, or antagonistic, behavior such as hostility. Furthermore, when compared to anxiety levels and cognitive effort (e.g., impression management and self-presentation) in intragroup contexts, levels and depletion of resources may be exacerbated in the intergroup situation.
Trait
Anxiety can be either a short-term "state" or a long-term personality "trait." Trait anxiety reflects a stable tendency across the lifespan of responding with acute, state anxiety in the anticipation of threatening situations (whether they are actually deemed threatening or not). A meta-analysis showed that a high level of neuroticism is a risk factor for development of anxiety symptoms and disorders. Such anxiety may be conscious or unconscious.
Personality can also be a trait leading to anxiety and depression. Through experience, many find it difficult to collect themselves due to their own personal nature.
Choice or decision
Anxiety induced by the need to choose between similar options is increasingly being recognized as a problem for individuals and for organizations. In 2004, Capgemini wrote: "Today we're all faced with greater choice, more competition and less time to consider our options or seek out the right advice."
In a decision context, unpredictability or uncertainty may trigger emotional responses in anxious individuals that systematically alter decision-making. There are primarily two forms of this anxiety type. The first form refers to a choice in which there are multiple potential outcomes with known or calculable probabilities. The second form refers to the uncertainty and ambiguity related to a decision context in which there are multiple possible outcomes with unknown probabilities.
Panic disorder | [
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922_6 | Panic disorder
Panic disorder may share symptoms of stress and anxiety, but it is actually very different. Panic disorder is an anxiety disorder that occurs without any triggers. According to the U.S Department of Health and Human Services, this disorder can be distinguished by unexpected and repeated episodes of intense fear. Someone who suffers from panic disorder will eventually develop constant fear of another attack and as this progresses it will begin to affect daily functioning and an individual's general quality of life. It is reported by the Cleveland Clinic that panic disorder affects 2 to 3 percent of adult Americans and can begin around the time of the teenage and early adult years. Some symptoms include: difficulty breathing, chest pain, dizziness, trembling or shaking, feeling faint, nausea, fear that you are losing control or are about to die. Even though they suffer from these symptoms during an attack, the main symptom is the persistent fear of having future panic attacks.
Anxiety disorders
Anxiety disorders are a group of mental disorders characterized by exaggerated feelings of anxiety and fear responses. Anxiety is a worry about future events and fear is a reaction to current events. These feelings may cause physical symptoms, such as a fast heart rate and shakiness. There are a number of anxiety disorders: including generalized anxiety disorder, specific phobia, social anxiety disorder, separation anxiety disorder, agoraphobia, panic disorder, and selective mutism. The disorder differs by what results in the symptoms. People often have more than one anxiety disorder.
Anxiety disorders are caused by a complex combination of genetic and environmental factors. To be diagnosed, symptoms typically need to be present for at least six months, be more than would be expected for the situation, and decrease a person's ability to function in their daily lives. Other problems that may result in similar symptoms include hyperthyroidism, heart disease, caffeine, alcohol, or cannabis use, and withdrawal from certain drugs, among others.
Without treatment, anxiety disorders tend to remain. Treatment may include lifestyle changes, counselling, and medications. Counselling is typically with a type of cognitive behavioural therapy. Medications, such as antidepressants or beta blockers, may improve symptoms. | [
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922_7 | About 12% of people are affected by an anxiety disorder in a given year and between 5–30% are affected at some point in their life. They occur about twice as often in women than they do in men, and generally begin before the age of 25. The most common are specific phobia which affects nearly 12% and social anxiety disorder which affects 10% at some point in their life. They affect those between the ages of 15 and 35 the most and become less common after the age of 55. Rates appear to be higher in the United States and Europe.
Short- and long-term anxiety
Anxiety can be either a short-term "state" or a long-term "trait." Whereas trait anxiety represents worrying about future events, anxiety disorders are a group of mental disorders characterized by feelings of anxiety and fears.
Four Ways to Be Anxious
In his book Anxious: the modern mind in the age of anxiety Joseph LeDoux examines four experiences of anxiety through a brain-based lens: | [
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922_8 | In the presence of an existing or imminent external threat, you worry about the event and its implications for your physical and/or psychological well-being. When a threat signal occurs, it signifies either that danger is present or near in space and time or that it might be coming in the future. Nonconscius threats processing by the brain activates defensive survival circuits, resulting in changes in information processing in the brain, controlled in part by increases in arousal and behavioral and physiological responses in the body that then produce signals that feed back to the brain and complement the physiological changes there, intensifying them and extending their duration.
When you notice body sensations, you worry about what they might mean for your physical and/or psychological well-being. The trigger stimulus does not have to be an external stimulus but can be an internal one, as some people are particularly sensitive to body signals.
Thoughts and memories may lead to you to worry about your physical and/or psychological well-being. We do not need to be presence of an external or internal stimulus to be anxious. An episodic memory of a past trauma or of a panic attack in the past is sufficient to activate the defence circuits.
Thoughts and memories may result in existential dread, such as worry about leading a meaningful life or the eventuality of death. Examples are contemplations of whether one's life has been meaningful, the inevitability of death, or the difficulty of making decisions that have a moral value. These do not necessarily activate defensive systems; they are more or less pure forms of cognitive anxiety.
Co-morbidity
Anxiety disorders often occur with other mental health disorders, particularly major depressive disorder, bipolar disorder, eating disorders, or certain personality disorders. It also commonly occurs with personality traits such as neuroticism. This observed co-occurrence is partly due to genetic and environmental influences shared between these traits and anxiety.
It is common for those with obsessive-compulsive disorder to experience anxiety. Anxiety is also commonly found in those who experience panic disorders, phobic anxiety disorders, severe stress, dissociative disorders, somatoform disorders, and some neurotic disorders.
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922_9 | Risk factors
Anxiety disorders are partly genetic, with twin studies suggesting 30-40% genetic influence on individual differences in anxiety. Environmental factors are also important. Twin studies show that individual-specific environments have a large influence on anxiety, whereas shared environmental influences (environments that affect twins in the same way) operate during childhood but decline through adolescence. Specific measured ‘environments’ that have been associated with anxiety include child abuse, family history of mental health disorders, and poverty. Anxiety is also associated with drug use, including alcohol, caffeine, and benzodiazepines (which are often prescribed to treat anxiety).
Neuroanatomy
Neural circuitry involving the amygdala (which regulates emotions like anxiety and fear, stimulating the HPA axis and sympathetic nervous system) and hippocampus (which is implicated in emotional memory along with the amygdala) is thought to underlie anxiety. People who have anxiety tend to show high activity in response to emotional stimuli in the amygdala. Some writers believe that excessive anxiety can lead to an overpotentiation of the limbic system (which includes the amygdala and nucleus accumbens), giving increased future anxiety, but this does not appear to have been proven.
Research upon adolescents who as infants had been highly apprehensive, vigilant, and fearful finds that their nucleus accumbens is more sensitive than that in other people when deciding to make an action that determined whether they received a reward. This suggests a link between circuits responsible for fear and also reward in anxious people. As researchers note, "a sense of 'responsibility', or self-agency, in a context of uncertainty (probabilistic outcomes) drives the neural system underlying appetitive motivation (i.e., nucleus accumbens) more strongly in temperamentally inhibited than noninhibited adolescents". | [
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